气体管道腐蚀试验中介质流动模式的模拟

R. K. Vagapov, K. A. Ibatullin, V. V. Yarkovoy
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引用次数: 0

摘要

通过管道生产和输送的气体和凝析气体中腐蚀性二氧化碳或硫化氢浓度升高,会对钢铁基础设施的内部表面造成严重的腐蚀损害。本文介绍了沿输气管道下部构件流动的介质的腐蚀作用的研究结果,这种腐蚀作用可以表现为动态、间歇或静态特征。在测试过程中,评估了介质流动的动态条件对u型槽的影响,以及气泡测试过程中水相对管道壁永久冲击的静态条件。燃气管道内变湿条件的建模表明,这种情况是典型的,发生在原料气生产和输送到气体加工和净化场所的过程中。我们模拟了天然气管道内部发生的危险操作因素:水生环境的组成、温度和腐蚀性气体的含量。在确定钢对局部形式腐蚀(点蚀、宽蚀和浅蚀坑)的耐蚀性时,我们发现,在腐蚀性二氧化碳和硫化氢条件下,钢的局部和一般腐蚀的发展速度可以达到2 - 3毫米/年。此外,实践证明,使用缓蚀剂对天然气设施的设备和管道进行保护,可以有效防止内部腐蚀过程的发生。获得的结果可用于评估作业介质的腐蚀活性,并选择最成熟的缓蚀剂进行气田的先导试验。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Simulation of the Modes of Medium Flow Movement through a Gas Pipeline during Corrosion Tests
Elevated concentrations of corrosive carbon dioxide or hydrogen sulfide in gas and gas condensate both produced and transported through pipelines lead to serious corrosion damage to the internal surfaces of steel infrastructure facilities. The paper presents the results of studying the corrosive effect of the medium flow along the lower component of the gas pipeline, which can exhibit a dynamic, intermittent or static character. During testing, the effect of both dynamic conditions of the medium flow on the U-shaped cell and static conditions of the permanent impact of the aqueous phase on the pipeline wall during the bubble test was evaluated. Modeling of variable wetting conditions inside the gas pipeline showed that such conditions are typical and occur upon production and transportation of raw gas to the places of gas processing and purification. We have simulated dangerous operational factors that occur inside the gas pipeline: the composition of the aquatic environment, temperature, and the content of corrosive gases. When determining the resistance of steels to local forms of corrosion (pitting, wide and shallow corrosion pits), we revealed that the rate of developing local and general corrosion of steel in aggressive carbon dioxide and hydrogen sulfide conditions can reach 2 – 3 mm/year. In addition, it has been shown that the use of corrosion inhibitors for protecting the equipment and pipelines of gas facilities can effectively prevent the occurrence of internal corrosion processes. The results obtained can be used in assessing the corrosion activity of operating media and selecting the most proven corrosion inhibitors for pilot testing at gas fields.
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