大气条件对丁腈橡胶与功能化蛋白废弃物聚合物复合材料的影响

Q4 Engineering
Mihaela NIŢUICĂ (VÎLSAN), Maria SÖNMEZ, Mihai GEORGESCU, Maria Daniela STELESCU, Dana GURĂU, Bogdan Florin RUSU, Andrei DUMITRU, Constantin-Vlad BĂRBULESCU
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引用次数: 0

摘要

在过去的20年里,技术取得了很大的进步,今天有可能获得具有性能的新型聚合物复合材料。对新型高性能材料不断增长的需求决定了基于弹性体和各种废物(蛋白质、纤维素、弹性体等)的新型聚合物结构的出现,这些废物来自各个领域(鞋、皮革制品等)。本文介绍了以丁腈橡胶(丁二烯-共丙烯腈)和鞋类和皮革制品工业的蛋白质废料为基础,低温研磨至微米尺寸,用聚二甲基硅氧烷(PDMS)改性的聚合物复合材料的制备和表征。PDMS具有增塑剂的作用,但同时它改善了混合在聚合物基质中的蛋白质废物的分散。采用混合法制备了聚合物复合材料,并按现行标准从物理力学角度进行了测试。样品在室温条件下调理24 h后,进行常温和70℃加速时效168 h的表征(热态,采用热风循环烘箱法)。此外,将聚合物复合材料样品置于365天的大气条件下(太阳、雨、风、冰雹、光等),以观察它们对所获得的聚合物复合材料性能的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of Atmospheric Conditions on the Polymer Composite Based on NBR Rubber and Functionalized Protein Waste
Technology has progressed a lot in the last 20 years, today it is possible to obtain new polymer composites that show performance properties. The ever-increasing demand for new high-performance materials has determined the appearance of new polymer structures based on elastomers and various wastes (protein, cellulosic, elastomeric, etc.) from various fields (shoes, leather goods, etc.). This paper describes the obtaining and characterization of polymer composites based on NBR rubber (butadiene-co-acrylonitrile) and protein waste from the footwear and leather goods industry, cryogenically ground to micrometric dimensions and modified with PDMS (polydimethyl siloxane). PDMS has the role of a plasticizer, but at the same time it improves the dispersion of protein waste mixed in the polymer matrix. The polymer composites were obtained by the mixing technique and tested from a physical-mechanical point of view according to the standards in force. The characterization in normal condition and accelerated aging at 70°C for 168 h (it was carried out hot, using the hot air circulation oven method) was carried out after the samples were subjected to conditioning for 24 h at ambient temperature. Also, the polymer composite samples were subjected for 365 days to atmospheric conditions (sun, rain, wind, hail, light, etc.) to see their influence on the properties of the obtained polymer composites.
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来源期刊
Leather and Footwear Journal
Leather and Footwear Journal Engineering-Industrial and Manufacturing Engineering
CiteScore
0.90
自引率
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发文量
14
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