基于固体硅酸盐和异位聚丙烯的复合材料的机械性能和热性能

Q. N. Berdinazarov, E. O. Khakberdiev, N. F. Normurodov, N. Z. Dusiyorov, N. R. Ashurov
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引用次数: 0

摘要

本文采用熔融混合法制备了基于聚丙烯(PP)和层状硅酸盐的高分子复合材料。以马来酸酐接枝聚丙烯(MA-p-PP)为增容剂,研究了增容剂用量对两种层状硅酸盐复合材料热性能和力学性能的影响。增容剂的含量分别为3%、6%、9%和12%,而填料的含量保持在3%。Cloisite15A是一种层状硅酸盐,改性剂密度较高,可生成插层结构,而Cloisite20A的改性剂密度相对较低,可生成多为剥落状纳米复合材料。纳米结构的形成导致热稳定性显著提高(聚丙烯及其基纳米复合材料在360°C和430°C的温度下分别失重50%)。力学性能分析表明,纳米复合材料的弹性模量增加了15 ~ 20%,且这种效应在剥离结构中表现得更为明显,但屈服应力基本保持不变,弹性变形显著减小。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
QATLAMLI SILIKATLAR VA IZOTAKTIK POLIPROPILEN ASOSIDAGI KOMPOZITLARNING MEXANIK VA TERMIK XUSUSIYATLARI
In this work, polymer composite materials based on polypropylene (PP) and layered silicates were obtained by melt mixing method. The research looked into the effect of the amount of compatibilizer on thermal and mechanical properties of composites based on two types of layered silicates with modifiers of different interlayer densities, with maleic anhydride grafted polypropylene (MA-p-PP), which was used as a compatibilizer. The compatibilizer was changed to 3, 6, 9 and 12 % while the amount of filler in the composite remained at 3 %. Cloisite15A, a layered silicate with a higher modifier density, produced intercalated structures, while Cloisite20A, with a relatively lower modifier density, produced mostly exfoliated nanocomposites. Forming of the nanostructure led to a significant increase in thermal stability (50 % weight loss was observed at temperatures of 360 and 430 °C for polypropylene and its based nano-composites, respectively). The analysis of the mechanical properties of nanocomposites showed that the elastic modulus increases by 15–20 %, and this effect is more expressive for exfoliated structures, however, the yield stress remains practically unchanged, and a significant decrease in elastic deformation is observed.
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