{"title":"二甲基锌-碲化二甲基体系液-气平衡等温图的求取方法","authors":"Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev, Tetiana Hnativ","doi":"10.23939/chcht17.03.469","DOIUrl":null,"url":null,"abstract":"According to the obtained experimental temperature dependences of the saturated vapor pressure on dimethylzinc – dimethyltelluride solutions with dimethylzinc content of 50.0 and 70.32 mol. %, isothermal sections (280, 290, 300, 310, and 320 K) were made. For the dimethylzinc – dimethyltelluride system based on a limited set of experimental data for the “liquid-vapor” equilibrium, the vapor composition was calculated according to the Duhem – Margules equation, as well as the partial pressures and the distribution coefficient.","PeriodicalId":9762,"journal":{"name":"Chemistry and Chemical Technology","volume":"40 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Method for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride\",\"authors\":\"Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev, Tetiana Hnativ\",\"doi\":\"10.23939/chcht17.03.469\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"According to the obtained experimental temperature dependences of the saturated vapor pressure on dimethylzinc – dimethyltelluride solutions with dimethylzinc content of 50.0 and 70.32 mol. %, isothermal sections (280, 290, 300, 310, and 320 K) were made. For the dimethylzinc – dimethyltelluride system based on a limited set of experimental data for the “liquid-vapor” equilibrium, the vapor composition was calculated according to the Duhem – Margules equation, as well as the partial pressures and the distribution coefficient.\",\"PeriodicalId\":9762,\"journal\":{\"name\":\"Chemistry and Chemical Technology\",\"volume\":\"40 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry and Chemical Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.23939/chcht17.03.469\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry and Chemical Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.23939/chcht17.03.469","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Method for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride
According to the obtained experimental temperature dependences of the saturated vapor pressure on dimethylzinc – dimethyltelluride solutions with dimethylzinc content of 50.0 and 70.32 mol. %, isothermal sections (280, 290, 300, 310, and 320 K) were made. For the dimethylzinc – dimethyltelluride system based on a limited set of experimental data for the “liquid-vapor” equilibrium, the vapor composition was calculated according to the Duhem – Margules equation, as well as the partial pressures and the distribution coefficient.