以羧甲基纤维素为储氢材料的碳气凝胶的合成与表征

IF 1.2 Q3 MULTIDISCIPLINARY SCIENCES
Ahmad Solehin Ab Sabar, Syaza Azhari, Nur Atiqah Nasir, Muhammad Zamir Othman
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引用次数: 0

摘要

本研究证明了一种直接、简单、低成本的碳气凝胶镁(CA-Mg)复合材料合成方法。它是通过溶胶-凝胶和冷冻干燥工艺将羧甲基纤维素钠(CMC)气凝胶碳化。Mg在制备步骤中用作CA的增强剂,并作为储氢装置的选择性候选物。请注意,CA-Mg复合材料的结构和形态是用场发射扫描电子显微镜(FESEM)、傅里叶变换红外光谱(FTIR)和x射线衍射(XRD)技术表征的。利用brunauer - emmet - teller (BET)和程序升温解吸法分析了CA-Mg复合材料作为储氢装置的能力。CA-Mg复合材料为多孔结构,具有101.4407 m2 /g的高比表面积,0.002 mol Mg2+是合成CA-Mg复合材料的最佳浓度。CA-Mg复合材料的初始脱氢温度为377.22℃,解吸氢气量最大,是储氢器件的潜在候选材料。这项研究强调了使用CA作为储氢装置的潜力,它实现了可持续发展目标(sdg)的第七个目标,即负担得起的清洁能源,以及能源部(DOE)使用碳基材料的目标。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Characterisation of Carbon Aerogel Derived from Carboxymethyl Cellulose as Hydrogen Storage Material
A direct, simple and low-cost approach to synthesising carbon aerogelmagnesium (CA-Mg) composites has been demonstrated in this research. It is conducted by carbonising sodium carboxymethyl cellulose (CMC) aerogels via a sol-gel and freezedrying process. Mg is used as an enhancer for CA in the preparation step and as a selective candidate for the hydrogen storage device. Note that the structure and morphology of CA-Mg composites are characterised using field emission scanning electron microscopy (FESEM), fourier transforms infrared spectroscopy (FTIR) and X-ray diffraction (XRD) techniques. The ability of CA-Mg composites to act as a hydrogen storage device is analysed by utilising Brunauer-Emmett-Teller (BET) and temperature-programmed desorption analysis. The CA-Mg composites comprise porous structures with a high specific surface area of 101.4407 m2 /g, and 0.002 mol of Mg2+ is the optimum concentration for synthesising CA-Mg composites. As a potential candidate for a hydrogen storage device, the CA-Mg composites show an initial dehydrogenation temperature of 377.22°C, where they desorbed the maximum amount of hydrogen gas. This study emphasises the potential for using CA as a hydrogen storage device, which fulfils the seventh goal of the Sustainable Development Goals (SDGs), affordable and clean energy, as well as Department of Energy (DOE)’s goal of using carbon-based materials.
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来源期刊
Journal of Physical Science
Journal of Physical Science Physics and Astronomy-Physics and Astronomy (all)
CiteScore
1.70
自引率
0.00%
发文量
19
期刊介绍: The aim of the journal is to disseminate latest scientific ideas and findings in the field of physical sciences among scientists in Malaysia and international regions. This journal is devoted to the publication of articles dealing with research works in Chemistry, Physics and Engineering. Review articles will also be considered. Manuscripts must be of scientific value and will be submitted to independent referees for review. Contributions must be written in English and must not have been published elsewhere.
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