{"title":"可持续Quercetin@Functionalized碳纳米管作为半tcfs和/或3D打印油墨在明胶的存在","authors":"M. Fares, Samah Radaydeh","doi":"10.2139/ssrn.3897767","DOIUrl":null,"url":null,"abstract":"Semi-Transparent conductive films (semi-TCFs) were fabricated from sustainable onion quercetin and functionalized carbon nanotubes (F-CNTs) in presence of different metal ion crosslinking agents via layer-by-layer technique. Moreover, 3D printing inks and injectable hydrogels were fabricated from sustainable onion quercetin and functionalized carbon nanotubes (F-CNTs) in presence gelatin. Synthesis and characterization of sustainable quercetin and functionalized CNTs were performed using spectroscopic, thermal, microscopic techniques; 1H-NMR, and ATR-FTIR for chemical structure, XRD for crystal structure, TGA and DTG for thermal stability, and SEM for morphologic nanostructure. Layer-by-layer semi-TCFs were fabricated in presence of crosslinking agent of metal ions like Ca2+, Ti2+, Sn2+, and Fe3+ ions, where transmittance was in the range of 41-67%, sheet resistance in 17-1567 kΩ/sq, and σdc/σop in 0.0005-0.02 range, which undoubtly confirm their semi-TCFs characteristics. Optimum performance of single-layer F-CNTs semi-TCFs was as follows; transmittance= 46.6%, sheet resistance= 6.5 kΩ/sq, and σdc/σop= 0.06. On the other hand, 3D printing ink of sustainable quercetin and Functionalized CNTs in presence of gelatin was fabricated. Semi-Interpenetrating network hydrogel was verified through spectroscopic ATR-FTIR technique. The injectable hydrogel showed promising characteristics of robustness, elasticity, anti-microbial activity, biocompatibility with human body, and stretchable low cost that adapt them to be successfully employed in biomedical and surgical applications.","PeriodicalId":131242,"journal":{"name":"EngRN: Biomedical Engineering (Topic)","volume":"52 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sustainable Quercetin@Functionalized Carbon Nanotubes as Semi-TCFsAnd/Or 3D Printing Inks in Presence of Gelatin\",\"authors\":\"M. Fares, Samah Radaydeh\",\"doi\":\"10.2139/ssrn.3897767\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Semi-Transparent conductive films (semi-TCFs) were fabricated from sustainable onion quercetin and functionalized carbon nanotubes (F-CNTs) in presence of different metal ion crosslinking agents via layer-by-layer technique. Moreover, 3D printing inks and injectable hydrogels were fabricated from sustainable onion quercetin and functionalized carbon nanotubes (F-CNTs) in presence gelatin. Synthesis and characterization of sustainable quercetin and functionalized CNTs were performed using spectroscopic, thermal, microscopic techniques; 1H-NMR, and ATR-FTIR for chemical structure, XRD for crystal structure, TGA and DTG for thermal stability, and SEM for morphologic nanostructure. Layer-by-layer semi-TCFs were fabricated in presence of crosslinking agent of metal ions like Ca2+, Ti2+, Sn2+, and Fe3+ ions, where transmittance was in the range of 41-67%, sheet resistance in 17-1567 kΩ/sq, and σdc/σop in 0.0005-0.02 range, which undoubtly confirm their semi-TCFs characteristics. Optimum performance of single-layer F-CNTs semi-TCFs was as follows; transmittance= 46.6%, sheet resistance= 6.5 kΩ/sq, and σdc/σop= 0.06. On the other hand, 3D printing ink of sustainable quercetin and Functionalized CNTs in presence of gelatin was fabricated. Semi-Interpenetrating network hydrogel was verified through spectroscopic ATR-FTIR technique. The injectable hydrogel showed promising characteristics of robustness, elasticity, anti-microbial activity, biocompatibility with human body, and stretchable low cost that adapt them to be successfully employed in biomedical and surgical applications.\",\"PeriodicalId\":131242,\"journal\":{\"name\":\"EngRN: Biomedical Engineering (Topic)\",\"volume\":\"52 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"EngRN: Biomedical Engineering (Topic)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2139/ssrn.3897767\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"EngRN: Biomedical Engineering (Topic)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2139/ssrn.3897767","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Sustainable Quercetin@Functionalized Carbon Nanotubes as Semi-TCFsAnd/Or 3D Printing Inks in Presence of Gelatin
Semi-Transparent conductive films (semi-TCFs) were fabricated from sustainable onion quercetin and functionalized carbon nanotubes (F-CNTs) in presence of different metal ion crosslinking agents via layer-by-layer technique. Moreover, 3D printing inks and injectable hydrogels were fabricated from sustainable onion quercetin and functionalized carbon nanotubes (F-CNTs) in presence gelatin. Synthesis and characterization of sustainable quercetin and functionalized CNTs were performed using spectroscopic, thermal, microscopic techniques; 1H-NMR, and ATR-FTIR for chemical structure, XRD for crystal structure, TGA and DTG for thermal stability, and SEM for morphologic nanostructure. Layer-by-layer semi-TCFs were fabricated in presence of crosslinking agent of metal ions like Ca2+, Ti2+, Sn2+, and Fe3+ ions, where transmittance was in the range of 41-67%, sheet resistance in 17-1567 kΩ/sq, and σdc/σop in 0.0005-0.02 range, which undoubtly confirm their semi-TCFs characteristics. Optimum performance of single-layer F-CNTs semi-TCFs was as follows; transmittance= 46.6%, sheet resistance= 6.5 kΩ/sq, and σdc/σop= 0.06. On the other hand, 3D printing ink of sustainable quercetin and Functionalized CNTs in presence of gelatin was fabricated. Semi-Interpenetrating network hydrogel was verified through spectroscopic ATR-FTIR technique. The injectable hydrogel showed promising characteristics of robustness, elasticity, anti-microbial activity, biocompatibility with human body, and stretchable low cost that adapt them to be successfully employed in biomedical and surgical applications.