非均相电Fenton工艺处理纺织废水的优化研究

N. D. Duc, Thi Thuy Le An, N. T. Phong
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引用次数: 0

摘要

为了生产出好的纺织产品,人们发明了许多稳定的合成染料。然而,排放到环境中的纺织废水中含有大量的染料,这些染料对热和太阳辐射具有生物抗逆性和稳定性。这些有毒污染物长期对环境产生负面影响,毒害植物、动物和人类。采用非均相电Fenton (HEF)系统处理纺织废水。采用共沉淀法合成的$Fe_{3}O_{4}-CeO_{2}$作为催化剂,选用稳定性好、导电性好的石墨电极。电流密度、pH和催化剂投加量是影响去除率的主要因素。采用响应面法对各影响因素建立经验数学模型,从而找到合适的处理工况,实现高去除率和低运行成本。在以前的研究中,被调查的范围是:电流密度$(1\theta - 2\theta nWcm2)$, pH $(3 - 5)$;催化剂用量$(\theta.5-1.5$凝胶)。在电流密度为16.89 $m\mathcal {X}cm^{2}、pH$ 3.15、催化剂投加量为1.24 g/l时,达到了最佳处理条件,COD去除率为95.5%,去色率为97美元。\theta $ %,符合国家标准(QCVN 13:15 15/BTNMT, A列)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimization of Heterogeneous Electro Fenton Process for Textile Wastewater Treatment
To produce good textile products, many stable synthetic dyes are invented However, textile wastewater discharged into the environment containing a large amount of dyes which are bio-recalcitrant and stable to heat and solar radiation. These toxic contaminants impact negatively the environment for a long time and poison plant, animal and human. In this study, Heterogeneous Electro Fenton (HEF) system was applied to treat textile wastewater. $Fe_{3}O_{4}-CeO_{2}$ synthesized by co-precipitation method was used as a catalyst and graphite electrodes were chosen for their stability and good conductivity. Three operating factors greatly affected the removal efficiency are current density, pH and catalyst dosage. Response surface methodology was applied to find empirical mathematical models for these factors, then find an accordant operating condition for treatment which provides high removal efficiency and low operating cost. Investigated ranges scaled in previous studies were: current density $(1\theta - 2\theta nWcm2)$, $pH (3 - 5)$; catalyst dosage $(\theta.5-1.5$ gel). At current density of 16.89 $m\mathcal {X}cm^{2}, pH$ of 3.15, catalyst dosage of 1.24 g/l, the treatment reached its optimum condition, under that COD and color removal efficiencies are 95.5 % and $ 97.\theta $ %, respectively, which met the national standard (QCVN 13:2015/BTNMT, Column A).
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