{"title":"金属-热硼还原热力学模拟","authors":"V. Zhuchkov, I. N. Kel’, V. Salina, A. Sychev","doi":"10.32339/0135-5910-2019-12-1360-1365","DOIUrl":null,"url":null,"abstract":". To improve the quality of steel and cast iron, the micro-alloyed by boron is applied, which is introduced into the melt within a scope of complex ferroalloys. There is information about rather effective application of silicon and aluminum as reducing agents, introduced within a scope of complex ferroalloy with manganese, chrome, tungsten and molybdenum. However, no information was found about application of such a ferroalloy for reducing of boron. Therefore, the purpose of the study was the thermodynamic simulation of boron simultaneous reducing by silicon and aluminum from the CaO–SiO 2 –MgO–B 2 O 3 oxide system. The influ-ence of aluminum content within a complex reducing agent on the boron reducing degree from the oxide system of the following compositions %: 36,7 CaO; 5,6 SiO 2 ; 2,8 MgO; 54,9 B 2 О 3 was studied. For particular study, the alloys of the following composition were taken: %: 60 Si – 5 Al – 35 Fe; 55 Si – 10 Al – 35 Fe; 50 Si – 15 Al – 35 Fe and 65 Si – 35 Fe. The simulation was accom-plished within a package of applied programs HSC Chemistry 6.12 with application of Equilibrium Composition module within the temperature range 1400–1600 ° С with a step of 50 ° С . It was determined, that replace of silicon in the alloys by aluminum results in considerable growth of reducing degree, which can reach 99%. Alloys с [Al] orig = 0–52 % have the lowest reducing degree. Presence of с [Al] orig = 5 % in the original alloy enables to increase the reducing degree until 69%. The further growth of the original aluminum content until 10 and 15% enables to reach the reducing degree of 85 and 94%. Based on the study results the conclusion was made about preference to apply aluminum from the Fe–Si–Al complex ferroalloy for boron reducing from the oxide system, since the degree of boron reduction degree is much higher comparing with application only silicon at the same total reducing agent (Si + Al = 65 %) quantity.","PeriodicalId":259995,"journal":{"name":"Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information","volume":"48 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermodynamic simulation of metal-thermal boron reducing\",\"authors\":\"V. Zhuchkov, I. N. Kel’, V. Salina, A. Sychev\",\"doi\":\"10.32339/0135-5910-2019-12-1360-1365\",\"DOIUrl\":null,\"url\":null,\"abstract\":\". To improve the quality of steel and cast iron, the micro-alloyed by boron is applied, which is introduced into the melt within a scope of complex ferroalloys. There is information about rather effective application of silicon and aluminum as reducing agents, introduced within a scope of complex ferroalloy with manganese, chrome, tungsten and molybdenum. However, no information was found about application of such a ferroalloy for reducing of boron. Therefore, the purpose of the study was the thermodynamic simulation of boron simultaneous reducing by silicon and aluminum from the CaO–SiO 2 –MgO–B 2 O 3 oxide system. The influ-ence of aluminum content within a complex reducing agent on the boron reducing degree from the oxide system of the following compositions %: 36,7 CaO; 5,6 SiO 2 ; 2,8 MgO; 54,9 B 2 О 3 was studied. For particular study, the alloys of the following composition were taken: %: 60 Si – 5 Al – 35 Fe; 55 Si – 10 Al – 35 Fe; 50 Si – 15 Al – 35 Fe and 65 Si – 35 Fe. The simulation was accom-plished within a package of applied programs HSC Chemistry 6.12 with application of Equilibrium Composition module within the temperature range 1400–1600 ° С with a step of 50 ° С . It was determined, that replace of silicon in the alloys by aluminum results in considerable growth of reducing degree, which can reach 99%. Alloys с [Al] orig = 0–52 % have the lowest reducing degree. Presence of с [Al] orig = 5 % in the original alloy enables to increase the reducing degree until 69%. The further growth of the original aluminum content until 10 and 15% enables to reach the reducing degree of 85 and 94%. Based on the study results the conclusion was made about preference to apply aluminum from the Fe–Si–Al complex ferroalloy for boron reducing from the oxide system, since the degree of boron reduction degree is much higher comparing with application only silicon at the same total reducing agent (Si + Al = 65 %) quantity.\",\"PeriodicalId\":259995,\"journal\":{\"name\":\"Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information\",\"volume\":\"48 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-12-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ferrous Metallurgy. 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引用次数: 0
摘要
. 为了提高钢和铸铁的质量,硼微合金化被引入到复杂铁合金范围内的熔体中。在锰、铬、钨、钼复合铁合金的范围内,介绍了硅和铝作为还原剂的较有效应用。然而,目前还没有发现这种铁合金在硼还原中的应用。因此,本研究的目的是模拟cao - sio2 - mgo - b2o3氧化体系中硅和铝同时还原硼的热力学过程。复合还原剂中铝含量对以下组合物氧化体系中硼还原度的影响%:36,7 CaO;5,6 sio2;2、8分别;54,9 b2 О 3进行了研究。在具体的研究中,采用了以下成分的合金:%:60 Si - 5 Al - 35 Fe;55 Si - 10 Al - 35 Fe;50si - 15al - 35fe和65si - 35fe。模拟在HSC Chemistry 6.12应用程序包中完成,应用平衡成分模块,温度范围为1400-1600°С,步长为50°С。结果表明,用铝代替硅后,合金的还原度明显提高,可达99%。[Al]合金的还原度最低。原合金中含有5%的[Al]合金,可使合金的还原度提高到69%。原铝含量进一步增加至10%和15%,可达到85%和94%的还原度。根据研究结果,在总还原剂(Si + Al = 65%)用量相同的情况下,硼的还原程度远高于只使用硅,因此在氧化体系中首选使用Fe-Si-Al复合铁合金中的铝来还原硼。
Thermodynamic simulation of metal-thermal boron reducing
. To improve the quality of steel and cast iron, the micro-alloyed by boron is applied, which is introduced into the melt within a scope of complex ferroalloys. There is information about rather effective application of silicon and aluminum as reducing agents, introduced within a scope of complex ferroalloy with manganese, chrome, tungsten and molybdenum. However, no information was found about application of such a ferroalloy for reducing of boron. Therefore, the purpose of the study was the thermodynamic simulation of boron simultaneous reducing by silicon and aluminum from the CaO–SiO 2 –MgO–B 2 O 3 oxide system. The influ-ence of aluminum content within a complex reducing agent on the boron reducing degree from the oxide system of the following compositions %: 36,7 CaO; 5,6 SiO 2 ; 2,8 MgO; 54,9 B 2 О 3 was studied. For particular study, the alloys of the following composition were taken: %: 60 Si – 5 Al – 35 Fe; 55 Si – 10 Al – 35 Fe; 50 Si – 15 Al – 35 Fe and 65 Si – 35 Fe. The simulation was accom-plished within a package of applied programs HSC Chemistry 6.12 with application of Equilibrium Composition module within the temperature range 1400–1600 ° С with a step of 50 ° С . It was determined, that replace of silicon in the alloys by aluminum results in considerable growth of reducing degree, which can reach 99%. Alloys с [Al] orig = 0–52 % have the lowest reducing degree. Presence of с [Al] orig = 5 % in the original alloy enables to increase the reducing degree until 69%. The further growth of the original aluminum content until 10 and 15% enables to reach the reducing degree of 85 and 94%. Based on the study results the conclusion was made about preference to apply aluminum from the Fe–Si–Al complex ferroalloy for boron reducing from the oxide system, since the degree of boron reduction degree is much higher comparing with application only silicon at the same total reducing agent (Si + Al = 65 %) quantity.