MASnI3钙钛矿太阳能电池中电子和空穴传输层的优化

Abhilash Prasad Sharma, S. Chanana
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引用次数: 0

摘要

考虑到钙钛矿太阳能电池的特点和应用,由于其具有相当低成本的制造方法,在薄膜光伏领域的研究受到了广泛的关注,从而在日常生活中的光伏应用中显示出优势。混合卤化物钙钛矿的功率转换效率可达25%以上,但其铅的毒性是主要问题。因此,挖掘出一些无毒、环保的钙钛矿材料,如甲基铵碘化锡(MASnI3),作为太阳能电池吸收材料是非常重要的。数值分析在实际问题的设计中起着至关重要的作用,因此可以很容易地进行不同假设的实验。本文利用一维太阳能电池电容器模拟器(SCAPS-1D)软件,演示了基于MASnI3的太阳能电池在不同空穴传输层(HTL)和电子传输层(ETL)组合下的仿真。结果表明,TiO2与P3HT复合产生的Jsc(电流密度)最高,为32.52 mA/cm2,功率转换效率最高,为25.75%。本研究可为钙钛矿太阳能电池选择ETL和HTL材料以获得更好的性能提供更准确的认识。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimization of Electron and Hole Transport Layers in MASnI3 Perovskite Solar Cell
Considering the characteristics and applications of Perovskite solar cell, it has garnered much attention in the field of research in thin-film photovoltaics owing to its comparable low-cost fabrication methods and hence showing its dominance in photovoltaic applications in daily life. The mixed halide perovskite has shown a promising power conversion efficiency of more than 25%, but the toxicity of lead is the main concern. Hence, it is important to dig out some nontoxic, environment friendly perovskite materials, which can be used as solar cell absorber materials, such as methyl ammonium tin iodide (MASnI3). Numerical analysis is used since it plays a critical role in the designing of realistic problems with ease and hence experimenting with different hypothesis can be easily carried out. In this paper, we have used 1-dimensional solar cell capacitor simulator (SCAPS-1D) software to demonstrate the simulation of MASnI3- based solar cell with various HTL (hole transport layer) and ETL (electron transport layer) combinations. Results show that the TiO2 and P3HT combination produced the highest Jsc (current density) of 32.52 mA/cm2 with the best power conversion efficiency of 25.75%. This study can offer a better accurate picture of understanding in choosing ETL and HTL materials for the better performance of the perovskite solar cell.
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