巨大的,游牧的极化

H. A. Pohl, D. Pohl, J. K. Pollock
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引用次数: 0

摘要

最近发现的分子极化模式,游牧极化,可以提供巨大的电响应,因为它的运作。现在还需要在各种分子实现中对这一现象进行深入研究,以确定它是否可以提供具有有利电性能的材料。迄今为止的证据表明确实如此。某些聚合物有机固体,包含离域电子分子轨道的扩展域,证明是最好的例子。这类材料的分子设计沿着这条线表现出非常高的介电常数(超介电),具有有用的低介电损耗,优异的化学和热稳定性,或具有非常高的压电电阻或压电极化响应。它的理论与观测结果很吻合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Giant, nomadic polarization
The recently discovered molecular mode of polarization, nomadic polarization, can provide giant electrical responses as it operates. It now remains to study the phenomenon thoroughly in various molecular realizations to see if it can provide materials with advantageous electrical properties. The evidence to date suggests that it does. Certain polymeric organic solids, containing extended domains of delocalized electronic molecular orbitals, prove to be prime examples. Such materials have been molecularly designed along these lines to show very high dielectric constants (superdielectrics), to have usefully low dielectric loss, excellent chemical and thermal stability, or to have very high piezo-resistance or piezo-polarization responses. The theory for it is in good agreement with observation.
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