被解雇了

一沁
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引用次数: 2

摘要

能量转化为相邻键的旋转。通过精心设计和合成聚合物包埋的环丁基环,作者表明,当超声诱导环开环时,某些相对取代基的几何形状得以保留。附带的模拟支持“飞掠”轨迹的启发,这种轨迹将能量狭窄地引导,以劈开循环的sigma键,然后迅速形成非循环的pi键。——《科学》,第7609期,第208页
本文章由计算机程序翻译,如有差异,请以英文原文为准。
FIRED UP
energy into adjacent bond rotations. Through careful design and synthesis of polymer-embedded cyclobutyl rings, the authors showed that certain relative substituent geometries are preserved when sonication induces ring opening. Accompanying simulations support the instigation of “flyby” trajectories that channel energy narrowly to cleave the cyclic sigma bonds and then rapidly form acyclic pi bonds. —JSY Science, abi7609, this issue p. 208
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