质子交换膜燃料电池的建模与参数观测

Younane Nassif, H. Hamdan
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引用次数: 11

摘要

质子交换膜(PEM)在为广泛的实际应用提供有效和复杂的解决方案方面发挥着潜在的作用。它被视为符合减排时间表和在效率和温室气体产生方面挑战其他技术的合适选择。在汽车系统中,该技术的优点是能够在低温下运行,消耗空气中的氧气,并且汽车启动时间短。这使得它成为汽车系统中使用的传统技术的一个具有挑战性的替代方案。燃料电池由一层膜组成,膜将两个电极(阴极和阳极)分开。这项工作只考虑阴极,阴极分为两个腔室:通道和气体扩散层(GDL)。燃料处理系统产生的氢气被送入电池堆的阳极,而空气通过空气压缩机被泵入阴极。燃料电池通过将化学能转化为电能来产生水和热。与所有化学反应一样,燃料电池的最佳效率取决于操作条件:空气流量、湿度、压力和温度。为了使反应物气体(氢气和空气)得到良好的输送,需要调节膜的水化作用。为此,本文研究了PEM燃料电池系统的内部参数辨识,特别是溢流现象的辨识。这是通过提出一个基于模型的观测器来实现的,它是在线监测方法的核心。所提出的方法很简单:它包括重建所选的内部参数,即GDL处的蒸汽分压和氧分压,旨在监测水化参数。该策略具有成本效益,并且其方法可以扩展到覆盖整个堆栈。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Modelling and Parameter Observation for Proton Exchange Membrane Fuel Cell
Proton-Exchange Membrane (PEM) plays a potential role in offering effective and sophisticated solutions to a wide range of real-world applications. It is seen as a suitable choice to fit the emission reduction schedules and to challenge other technologies in terms of efficiency and greenhouse gases production. In automotive systems, this technology offers the advantage of being able to operate at low temperature, consuming the oxygen from the air and having short automotive startup time. This makes it a challenging alternative to the traditional technologies used in automotive systems. The fuel cell consists of a membrane that separates two electrodes (cathode and anode). This work considers only the cathode which is divided into two chambers: the channel and the Gas Diffusion Layer (GDL). The hydrogen generated from the fuel processing system, is fed into the anode of the cell stack, while air is pumped into the cathode through an air compressor. Fuel cells produce water and heat by converting the chemical energy to electrical energy. As all chemical reactions, the fuel cell's optimal efficiency depends on the operating conditions: air flow, humidity, pressure, and temperature. For a good transportation of the reactant gases (hydrogen and air), the hydration of the membrane needs to be regulated. For this reason, this paper deals with the internal parameter identification of a PEM fuel cell system, especially the flooding phenomenon. This is performed by proposing a model-based observer, which is the core of an on-line monitoring method. The proposed procedure is simple: it consists of rebuilding the chosen internal parameters, which are the vapor and the oxygen partial pressures at the GDL, aiming to monitor the hydration parameter. This strategy is cost-effective and its approach can be extended to cover the whole stack.
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