聚四氟乙烯和聚偏氟乙烯膜对高浓度硫化氢(H2S)气体的渗透

A. Asnawati, Diah Ayu Nur Sholehah, Dwi Indarti, Tri Mulyono, Bambang Piluharto, Y. M. Muflihah
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引用次数: 0

摘要

硫化氢(H2S)是一种有毒、腐蚀性强、易燃的气体。采用PTFE(聚四氟乙烯)膜和PVDF(聚偏氟乙烯)膜的渗透方法可以减少H2S气体的存在。这种H2S气体通过膜,然后被SAOB(硫化物酸酐氧化剂缓冲液)以S2-的形式捕获。采用可见分光光度计对通过的H2S气体进行分析。采用聚四氟乙烯膜,最佳流速为14.71 mL/min,质量通量为0.825 kg/m2。小时,渗透系数为0.696 kg/m2.hour。bar, H2S气体去除率为88.14%。SAOB的最佳流速为0.30 mL/min,质量通量为0.843 kg/m2。h, H2S气体去除率为89.98%。在PVDF膜上得到的结果表明,优化过程中H2S气体产生的质量通量为0.742 kg/cm2。最佳SAOB溶液为0.754 kg/cm2.h。所得渗透率系数为0.741 kg/cm2.h。结果表明:本研究以4.76 mL/min的H2S气体最佳流速为94.89%,以0.3 mL/min的SAOB气体最佳流速为95.66%去除H2S气体
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Permeation of High Concentration Hydrogen Sulfide (H2S) Gas Using PTFE (Polytetrafluoroethylene) and PVDF (Polyvinylidene Fluoride) membranes
Hydrogen sulfide (H2S) is a toxic, corrosive, and flammable gas. The presence of H2S gas can be reduced by a permeation method using PTFE (Polytetrafluoroethylene) membranes and PVDF (polyvinylidene fluoride) membranes. This H2S gas passed through the membrane and was then captured by the SAOB (Sulfide Anhydride Oxidant Buffer) in S2- species form. A visible spectrophotometer was applied for the analysis of passed H2S gas. Using a PTFE membrane, the optimum flow rate was obtained at 14.71 mL/min, with a mass flux of 0.825 kg/m2.hour, permeability coefficient of 0.696 kg/m2.hour.bar, and percent removal of H2S gas was 88.14%. The optimum flow rate for the SAOB was obtained at a rate of 0.30 mL/min with a mass flux of 0.843 kg/m2.hour and a percent removal of H2S gas of 89.98%. Based on the results obtained on the PVDF membrane, the mass flux produced in the optimization of H2S gas is 0.742 kg/cm2.hour, and the optimization of the SAOB solution is 0.754 kg/cm2.hour. The resulting permeability coefficient value is 0.741 kg/cm2.hour. The results indicate that this study can remove H2S gas at the optimum H2S gas flow rate of 4.76 mL/minute of 94.89% and the optimum SAOB flow rate of 0.3 mL/minute of 95.66%
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