The measurements results adjustment by the Least Square Method

The method for processing of the measurement results obtained from Comite International des Poids et Measures (CIPM) Key, Regional Metrology Organizations (RMO) or supplementary comparisons, from the proficiency testing by interlaboratory comparisons and the calibrations is proposed. It is named by authors as adjustment by least square method (LSM). Additive and multiplicative parameters for each measuring standard of every particular laboratory will be the results of this adjustment. As well as the parameters for each artifact. The parameters of the measurements standards are their additive and multiplicative degrees of equivalence from the comparison and the estimations of the systematic errors (biases) from calibrations. The parameters of the artifacts are the key comparisons reference value from the comparison and the assigned quantity values from the calibrations. The adjustment is considered as a way to solving a problem of processing the great amount of homogeneous measurements with many measuring standards at a different comparison levels (CIPM, RMO or supplementary), including connected problems. Four different cases of the adjustments are considered. The first one is a free case of adjustment. It was named so because of the fact that none of participants has any advantage except their uncertainties of measurements. The second one is a fixed case of adjustment. Measuring results of RMO and supplementary comparisons are rigidly linked to additive and multiplicative parameters of measuring standards of particular laboratories participated in CIPM key comparisons. The third one is a case of adjustment with dependent equations. This one is not so rigidly linked of the new comparisons results to previous or to some other comparisons as for fixed case. It means that the new results of comparisons are influenced by the known additive and multiplicative parameters and vice versa. The fourth one is a free case of adjustment with additional summary equations. In that case certain checking equations are added to the system of equations. So, the sum of parameters multiplied by their weights of all measurement standards for particular laboratories participated in comparisons should be equal to zero.