电缆生产条件下填充高分子材料力学试验变形增长动力学模型

V. Zolotarev, O. Golik, Eugene Moskvitin, Mykola Zykоv, A. Shurupova, L. Shchebeniuk, Oksana Vasylieva
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引用次数: 0

摘要

随着高填充无卤塑料生产的引入,其运行中的机械强度直接取决于阻燃剂的含量和应用技术,控制电缆护套的机械特性在防火设计中变得非常重要。高分子材料及其组分是粘弹性材料,其力学性能与应力时间有关。介绍了生产条件下无卤电缆塑料规范试验机械特性测定过程中,在不同稀释率下,由单轴拉伸时间计算变形试样率伸长率的结果。结果表明:无卤塑料电缆护套内外两层的塑性规范参数值存在显著差异:由于挤压过程中的强制变形过程,即强制聚合物结构取向,导致护套内外两层的聚合物结构存在差异。给出了不同夹钳稀释速度下样品的伸长相对变形实验依赖δL(t)对单轴拉伸时间的依赖性,通过大数据阵列验证了不同结构相似填充无卤聚合物的依赖性形状可重复性δL(t)。提出了瞬时弹性、粘弹性和瞬时塑性(不可逆)的应变率与拉伸时间的关系模型:dε/dt = λпр exp(- t/λпр) +{∫λ1 exp(- τ/λ1).exp[- (t - τ)/λ2]dτ]}/Δt。给出了用该模型近似实验数据得到的指定试样变形分量的适当参数估计。该模型首先将存在特征相对变形最大值(t = tm)解释为具有不同余波λ的两个相互依赖的变形过程叠加。其次,它允许指定测试要求:随着夹具稀释速度的增加,最大时间tm显着降低,分别,夹具稀释速度越高,连续样品控制截面长度测量之间的间隔时间Δt越小。在250 mm/min的速度下,实验证实了这一结论
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Model of deformation growth dynamics during filled polymer materials mechanical tests under cable production conditions
With the introduction into highly filled halogen-free plastics production, the mechanical strength of which in operation directly depends on the flame retardant content and application technology, it becomes important to control the cable sheath mechanical characteristics in a fireproof design. Polymeric materials and their compositions are viscoelastic materials for which the mechanical properties depend on the stress time. The results of estimating the deformation samples rate elongation from the uniaxial stretching time at different dilution rates of the clamps in the mechanical characteristics determining process for halogen-free cable plastics in regulatory tests under production conditions are presented. It is shown that the inner and outer layers of the halogen-free plastic cable sheath have significantly different values of the plasticity normative parameter: differences evidence in the polymer structure in the inner and outer layers of the sheath due to the forced deformation process during extrusion, which is forced polymer structure orientation. Elongation relative deformation experimental dependences δL(t) of the samples on the uniaxial stretching time at different clamps dilution speeds are given, which illustrate confirmed by a large data array the dependencies shape reproducibility δL(t) for different in structure similar filled halogen-free polymers. The strain rate dependence model on tensile time as the sum of instantaneous-elastic, viscoelastic and instantaneous-plastic (irreversible) is proposed: dε/dt = λпр exp ( – t/λпр) + {∫ λ1 exp(–τ/λ1).exp[–(t–τ)/λ2]dτ]}/Δt. The appropriate parameter estimates of the named samples deformation components obtained by approximating the experimental data by the proposed model are given. The proposed model, firstly, explains the presence characteristic relative deformation maximum (t = tm) as a two interdependent deformation processes superposition with different aftermath λ. Secondly, it allows to specify the requirements for testing: with increasing the clamps dilution speed, the maximum time tm decreases significantly, respectively, the higher the clamps dilution speed, the smaller interval time Δt between a successive sample control section length measurements. This conclusion was experimentally confirmed for a specific material at a speed of 250 mm/min
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