{"title":"环糊精碳纳米管电极识别中性硝基苯酚的功能化研究","authors":"Zhouping Wang, G. Luo, S. Xiao","doi":"10.1109/ICSENS.2003.1279081","DOIUrl":null,"url":null,"abstract":"A novel interface architecture was constructed by a large aggregated pore of carbon nanotube (CNT) captured cyclodextrin (CD) with a small cavity. The isomer recognition ability of various cyclodextrin-incorporated carbon nanotube electrodes (CD-CNT/E) were firstly investigated and characterized systematically by differential pulse voltammetry experiments. Due to the functionalization of CNT with CD, modified electrodes exhibited perfect electrocatalytic response and enhanced recognition ability towards neutral nitrophenol (NP) isomers. The results indicated that /spl alpha/-CD-CNT/E had the best response to p-NP, /spl gamma/-CD-CNT/E did best for o- N P and HP-/spl beta/-CD-CNT/E showed excellent response to m- and p-NP, which originate from the porous structure of aggregated CNT, size selective effect and steric hindrance effect of substituent of CD. The electronic properties of CNT coupled with the specific recognition properties would indeed make for an ideal sensor.","PeriodicalId":369277,"journal":{"name":"Proceedings of IEEE Sensors 2003 (IEEE Cat. No.03CH37498)","volume":"40 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2003-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Functionalization of cyclodextrins-incorporated carbon nanotube electrodes for neutral nitrophenol recognition\",\"authors\":\"Zhouping Wang, G. Luo, S. Xiao\",\"doi\":\"10.1109/ICSENS.2003.1279081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel interface architecture was constructed by a large aggregated pore of carbon nanotube (CNT) captured cyclodextrin (CD) with a small cavity. The isomer recognition ability of various cyclodextrin-incorporated carbon nanotube electrodes (CD-CNT/E) were firstly investigated and characterized systematically by differential pulse voltammetry experiments. Due to the functionalization of CNT with CD, modified electrodes exhibited perfect electrocatalytic response and enhanced recognition ability towards neutral nitrophenol (NP) isomers. The results indicated that /spl alpha/-CD-CNT/E had the best response to p-NP, /spl gamma/-CD-CNT/E did best for o- N P and HP-/spl beta/-CD-CNT/E showed excellent response to m- and p-NP, which originate from the porous structure of aggregated CNT, size selective effect and steric hindrance effect of substituent of CD. The electronic properties of CNT coupled with the specific recognition properties would indeed make for an ideal sensor.\",\"PeriodicalId\":369277,\"journal\":{\"name\":\"Proceedings of IEEE Sensors 2003 (IEEE Cat. No.03CH37498)\",\"volume\":\"40 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2003-10-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of IEEE Sensors 2003 (IEEE Cat. No.03CH37498)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ICSENS.2003.1279081\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of IEEE Sensors 2003 (IEEE Cat. No.03CH37498)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICSENS.2003.1279081","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Functionalization of cyclodextrins-incorporated carbon nanotube electrodes for neutral nitrophenol recognition
A novel interface architecture was constructed by a large aggregated pore of carbon nanotube (CNT) captured cyclodextrin (CD) with a small cavity. The isomer recognition ability of various cyclodextrin-incorporated carbon nanotube electrodes (CD-CNT/E) were firstly investigated and characterized systematically by differential pulse voltammetry experiments. Due to the functionalization of CNT with CD, modified electrodes exhibited perfect electrocatalytic response and enhanced recognition ability towards neutral nitrophenol (NP) isomers. The results indicated that /spl alpha/-CD-CNT/E had the best response to p-NP, /spl gamma/-CD-CNT/E did best for o- N P and HP-/spl beta/-CD-CNT/E showed excellent response to m- and p-NP, which originate from the porous structure of aggregated CNT, size selective effect and steric hindrance effect of substituent of CD. The electronic properties of CNT coupled with the specific recognition properties would indeed make for an ideal sensor.
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