[含碳化铌石膏粘结熔模在金属陶瓷修复用合金铸造中的应用]。

S Tsuruta, S Ban, J Hasegawa, S Hayashi, K Iiyama, Y Yamamura
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引用次数: 0

摘要

采用机械混合的方法,制备了含NbC重量为0.5 ~ 5.0 wt%的石膏粘结试验性投资料。对金属陶瓷修复用镍铬合金的凝固、热膨胀测量、抗压强度和铸造精度进行了研究。采用x射线衍射、热重差热分析(TG-DTA)和扫描电镜(SEM)对NbC加热过程进行了分析。NbC在300 ~ 600℃之间被氧化为Nb2O5,体积变化为:2NbC + 4 1/2O2----Nb2O5 + 2CO2根据JCPDS文件的晶格常数计算出的1/2Nb2O5的理论体积约为NbC的4倍。70 wt%方石英和30 wt%石膏(含2.0 wt%、3.0 wt%和5.0 wt% NbC)的实验投资,热膨胀率分别为7.0、10.0和13.0%。含2.0 wt% NbC的熔模对金属陶瓷修复用Ni-Cr合金的铸造精度与商用磷化熔模几乎相同。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Application of gypsum-bonded investment containing niobium carbide on casting of alloy for metal-ceramic restoration].

Experimental gypsum-bonded investments containing 0.5-5.0 wt% NbC were prepared by mechanical mixing of each powder. Setting and thermal expansion measurement, compressive strength and casting accuracy for Ni-Cr alloy for metal-ceramic restoration were investigated. Analysis of NbC during heating was carried out by X-ray diffraction, TG-DTA and SEM. NbC was oxidized to Nb2O5 with a volume change between 300-600 degrees C, as in the following equation: 2NbC + 4 1/2O2----Nb2O5 + 2CO2 The theoretical volume of 1/2Nb2O5 calculated from the lattice constants according to JCPDS file was approximately 4 times larger than that of NbC. The experimental investments of 70 wt% cristobalite and 30 wt% gypsum containing 2.0, 3.0 and 5.0 wt% NbC showed large thermal expansion of 7.0, 10.0 and 13.0% respectively. The investment containing 2.0 wt% NbC showed nearly the same casting accuracy for Ni-Cr alloys for metal-ceramic restoration as the commercial phosphate-bonded investment.

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