Dielectric behaviour and magnetoelectric effect in Ni0·25Co0·75Fe2O4-Ba0·8Pb0·2TiO3 ceramic composites

Abstract Dielectric and magnetoelectric properties are reported in magnetoelectric (ME) composites containing lead doped barium titanate as the electrical component and a mixed Ni-Co ferrite as the magnetic component. Changes were observed in dielectric properties as well as in the ME effect as the molar ratio of the components was varied. A maximum value of ME conversion factor of 0·42 mV cm - 1 Oe - 1 (52·78 VA - 1) was observed in the composite containing 15 mol-% ferrite. Larger ME effects were observed in composites with higher contents of ferroelectric phase. This conclusion differs from earlier theoretical studies which predict a large ME interaction in composites with a 1:1 molar ratio of participating phases. Apart from the technological importance of the ME effect, some anomalies in magnetic phase transition induced by electric fields are also of scientific interest. The variation in dielectric properties with temperature resulted in two maxima, corresponding to the ferroelectric and ferrimagnetic Curie temperatures. This behaviour is unlike anything previously observed in other ME composites.