[在职业卫生中使用宽孔柱毛细管气相色谱的例子]。

H Frank, L Senf, T Welsch
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引用次数: 0

摘要

宽孔毛细管柱(0.4-0.75 mm ID)可以轻松廉价地安装在填充柱gc中。分析的优势使这种毛细管和相互转换的硬件套件的市场不断扩大。举例说明,通常只有使用毛细管柱才能准确地确定单个暴露水平:乙苯也可以在复杂混合物中从c8异构体中分离出来,橡胶烟雾暴露的标记PBN可以在30分钟的采样时间内确定,FID的检测灵敏度也足以用于氯化农药和高沸点化合物的分析,这有利于大口径毛细管柱的高相比。单个毛细管柱可以替代各种不同的填充柱,从而节省时间和金钱,并保护分析人员免受失败和令人沮丧的妥协。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Examples for using capillary gas chromatography with wide bore columns in occupational health].

Wide bore capillary columns (0.4-0.75 mm ID) can be easily and inexpensively installed in packed column GCs. The analytical advantages cause an expanding market for such capillaries and interconverting hardware kits. It is illustrated with some examples that often individual exposition levels can be determined exactly only by using capillary columns: ethylbenzene may be separated from the C8-isomers also in complex mixtures, the marker PBN for rubber smoke expositions can be determined with 30 min sampling time, the detection sensitivity of the FID is sufficient also for chlorinated pesticides and the analyses of high-boiling compounds profit by the high phase ratio of wide bore capillary columns. A single capillary column substitutes a variety of different packed columns, so saving time and money and protecting the analyst from failures and frustrating compromises.

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