非线性光学研究界面上的吸附

Viola Vogel, Xuhua Xiao, C. Mullin, Y. Shen
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摘要

二阶非线性光学技术已被证明具有高度的表面特异性。单分子膜在各种界面上的吸附,例如金属/真空、玻璃/水或水/空气等,可以用亚单层灵敏度探测。详细的分子信息,如表面分子的平均取向分布、吸附物的表面浓度、吸附物的非线性等,都可以从测量中推断出来。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Adsorbates at Interfaces studied by Nonlinear Optics
Second-order nonlinear optical techniques have been demonstrated to be highly surface specific. The adsorption of monolayers at various interfaces, e.g., metal/vacuum, glass/water or water/air, etc., can be probed with a submonolayer sensitivity. Detailed molecular information, such as the mean orientational distribution of the surface molecules, the surface concentration of adsorbates, the nonlinearity of adsorbates, and so on, can be deduced from the measurements.
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