稀烷醇胺温度对醇胺溶液CO2吸收过程性能的影响

A. Kazemi
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引用次数: 1

摘要

利用烷醇胺法脱除天然气中的酸性气体是天然气脱硫中最常用的技术。根据酸味和甜味气体的规格,几种烷醇胺溶液可用于酸性气体的去除,所有这些都是成熟的工艺。然而,剩下的问题之一是与流程相关的成本。针对某高CO2/H2S比气田生产的天然气,设计了DEA、DGA和混合(MDEA+DEA)脱硫工艺。对于每个过程,设计了七个场景来研究冷却器的操作参数对过程性能的影响。对于每种情况,冷却器的任务是不同的,以便有一个特定的瘦胺温度进入吸收器。每个场景都使用Aspen HYSYS进行模拟,并使用Aspen经济评估进行经济评估。根据本研究的结果,当贫胺温度升高时,所需的溶液循环速率略有增加。然而,在较高的瘦胺温度下运行DEA和DGA工艺,可以获得较低的工艺资本成本和较低的冷却器负荷。此外,对于MDEA+DEA工艺,在较低的贫胺温度下操作会降低碳氢化合物的收率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effects of lean alkanolamine temperature on the performance of CO2 absorption processes using alkanolamine solutions
Acid gas removal from the natural gas using alkanolamine processes is the most common technology used for sweetening of natural gas. Based on the sour and sweet gas specifications, several alkanolamine solutions can be used for acid gas removal, all of which are well developed processes. However, one of the remaining issues is the costs associated with the processes. In this study, DEA, DGA and mixed (MDEA+DEA) processes are designed for sweetening the natural gas produced in one of the gas fields having high CO2/H2S ratio. For each process, seven scenarios are designed to investigate the effects of the cooler’s operating parameters on the performance of the process. For each scenario, the duty of the cooler is varied in order to have a specific lean amine temperature entering the absorber. Each scenario is simulated using Aspen HYSYS and economically evaluated using Aspen economic evaluation. Based on the results of this study, the required solution circulation rates slightly increases when the lean amine temperature increases. However, Lower process capital costs and lower cooler’s duty were obtained by operating the DEA and DGA processes at higher values of lean amine temperature. Also, operating at lower lean amine temperatures resulted in lower hydrocarbon pick up in case of MDEA+DEA process.
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