Ho‐Young Jung, Min‐Woo Kim, Jinho Lim, J. Choi, S. Roh
{"title":"sPEEK/sGO复合膜中sGO含量对一体化再生燃料电池的影响","authors":"Ho‐Young Jung, Min‐Woo Kim, Jinho Lim, J. Choi, S. Roh","doi":"10.18770/KEPCO.2016.02.01.127","DOIUrl":null,"url":null,"abstract":"Abstract Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPo nt’s Nafion which is a commercial polymer electrolyte membrane has high permeabili ty, high cost, and decreasing proton conductivity and dimensional stability over 80°C. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer elect rolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane’s water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.","PeriodicalId":445819,"journal":{"name":"KEPCO Journal on electric power and energy","volume":"43 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2016-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell\",\"authors\":\"Ho‐Young Jung, Min‐Woo Kim, Jinho Lim, J. Choi, S. Roh\",\"doi\":\"10.18770/KEPCO.2016.02.01.127\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPo nt’s Nafion which is a commercial polymer electrolyte membrane has high permeabili ty, high cost, and decreasing proton conductivity and dimensional stability over 80°C. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer elect rolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane’s water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.\",\"PeriodicalId\":445819,\"journal\":{\"name\":\"KEPCO Journal on electric power and energy\",\"volume\":\"43 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-03-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"KEPCO Journal on electric power and energy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18770/KEPCO.2016.02.01.127\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"KEPCO Journal on electric power and energy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18770/KEPCO.2016.02.01.127","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell
Abstract Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPo nt’s Nafion which is a commercial polymer electrolyte membrane has high permeabili ty, high cost, and decreasing proton conductivity and dimensional stability over 80°C. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer elect rolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane’s water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.