注氧喷枪重整气体燃烧热性能评价

Sirish Parvathaneni, M. Andrade, D. Boulanov
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引用次数: 0

摘要

在HYL直接还原铁(DRI)工艺中,从蒸汽/甲烷转化炉中产生的温度为~1150 K的转化气(由CO、CO2、CH4、H2和H2O组成)进行预热,为竖炉内的DRI工艺提供足够的温度(即~1250 K)。这种预热是通过O2/转化气体燃烧来实现的。在HYL过程中,O2通过一个“l形喷枪”注入重整气的流动路径。喷枪结构和O2/转化气的流量、温度等操作变量对燃烧性能有显著影响。例如,局部可燃气体成分的形成可能导致与爆炸有关的问题,而喷嘴出口O2速度不足导致喷嘴因闪回而磨损。因此,除了气流条件外,喷嘴的设计还决定着O2与转化气体的局部混合,最终影响局部反应机理和火焰的形成。本文利用计算流体动力学(CFD)研究了氧喷枪系统中的流体流动、反应机理和火焰稳定性。转化后的气体进入直径0.96 m、长度≈7m的水平圆柱形管。O2喷射枪穿过圆柱形管,O2出口位于管的中心。O2出口的喷嘴直径为3cm。采用Reynolds-average Navier-Stokes (RANS)耦合剪切应力输运(SST) k-ω湍流模型模拟了O2入口雷诺数~ 10的湍流流动。O2和转化气的进口质量流量和温度分别为0.66和19.7 kg/s,分别为303 K和1163 K。进口重整气由4.89 vol % CO2, 15 vol % CO, 67 vol % H2, 1.71 vol % H2O, 10.76 vol % CH4, 1.11 vol % N2组成。实现了CO、H2、CH4燃烧和水煤气转移反应。几何学和模型的更多细节将在会议上展示。由于喷枪穿透重整气的流道,在喷枪区域的上半部分形成了一个低压区,预测流场向上半部分倾斜。CO、H2、CH4的燃烧反应使点温度升高至4950 K。然而,预测的出口温度在管道截面上的平均温度为1270k。此外,由于主要的逆向水气转换反应,出口CO由15 vol %增加到17.83%。会议将进一步详细介绍流量变量和喷嘴设计对气体混合、反应速率、温度和物质分布、火焰稳定性(即闪回和火焰提升)和出口组成的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Thermal Performance Assessment of Reformed Gas Combustion in O2 Injection Lance
Extended Abstract In HYL direct reduced iron (DRI) process, the reformed gas (composed of CO, CO2, CH4, H2, and H2O) from the steam/methane reformer with a temperature of ~1150 K is subjected to pre-heating to provide sufficient temperature for the DRI process (i.e., ~1250 K) in the shaft furnace. Such pre-heating is achieved by the O2/reformed gas combustion. In the HYL process, the O2 is injected through an ‘L-shaped lance’ penetrating the flow path of reformed gas. The combustion performance is significantly influenced by the lance configuration and O2/reformed gas operating variables such as flow rates and temperature. For example, the formation of local ignitable gaseous composition may lead to issues related to explosion while insufficient O2 velocity at nozzle exit leads to nozzle wear out due to flashback. Therefore, the design of the nozzle in addition to gas flow conditions governs the local mixing of O2 and reformed gas which ultimately influences the local reaction mechanisms and flame formation. In the present work, the fluid flow, reaction mechanisms, and flame stability in the O2 injection lance system are investigated using computational fluid dynamics (CFD). The reformed gas enters into the horizontal cylindrical tube with diameter of 0.96 m and length of ≈ 7m. The O2 injection lance penetrates the cylindrical tube and the O2 exit is located at centre of the tube. The nozzle diameter at O2 exit is 3 cm. Reynolds-averaged Navier-Stokes (RANS) coupled with the shear stress transport (SST) k-ω turbulence model is used to simulate the turbulent flow (Reynolds number at O2 inlet ~ 10). The inlet mass flow rate and temperature of O2 and reformed gas are 0.66 and 19.7 kg/s, 303 K and 1163 K respectively. The reformed gas at the inlet is composed of 4.89 vol % CO2, 15 vol % CO, 67 vol % H2, 1.71 vol % H2O, 10.76 vol % CH4, 1.11 vol % N2. The CO, H2, CH4 combustion and water gas shift reactions are implemented [1]. Further details of the geometry and the model will be presented in the conference. Due to penetration of the lance into the flow path of reformed gas, a low-pressure region is created in the latter upper part of lance region and the flow field predicted is inclined towards the upper region. The CO, H2, CH4 combustion reactions led to an increase in the spot temperature up to 4950 K. However, the predicted outlet temperature averaged across the pipe cross section is 1270 K. Further, due to dominant backward water-gas shift reaction the CO at the outlet increased from 15 vol % to 17.83 %. Further details of the effect of flow variables and nozzle design on the gaseous mixing, reaction rates, temperature and species distribution, flame stability (i.e., flashback and flame lifting), and outlet composition will be presented in the conference.
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