碱缓冲层对倒置钙钛矿太阳能电池性能的影响

N. Touafek, C. Dridi, R. Mahamdi
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引用次数: 3

摘要

为了提高基于CH3NH3PbI3钙钛矿材料的倒p-i-n型平面异质结结构光伏电池的性能,在电子输运层(ETL) PCBM和金属触点之间引入了薄缓冲层Bathocuproine (BCP)。利用太阳能电池电容模拟器(SCAPS-1D)研究了钙钛矿太阳能电池(PSCs)中BCP的参数变化趋势。结果表明,BCP缓冲层厚度在5 nm处最优,功率转换效率(PCE)为17.30%,VOC为1.39 V, FF为62.89%。载流子浓度高于1017 cm-3时,转化效率可大幅提高约0.35 ~ 2.3%。此外,较低的金属功函数(Фm<4.3 eV)提高了电学参数,其中效率高达21.3%。关键词:太阳能电池,钙钛矿,CH3NH3PbI3, BCP, SCAPS,金属功函数
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Bathocuproine Buffer Layer Effect on the Performance of Inverted Perovskite Solar Cells
To boosting the performance of inverted p-i-n-type planar hetero-junction architecture photovoltaic cells based on CH3NH3PbI3 perovskite materials, a thin buffer layer Bathocuproine (BCP) is introduced between the Electron Transporting Layer (ETL) PCBM and the metal contact. The trends in parameters Perovskite Solar Cells (PSCs) inserting BCP is studied using solar cell capacitance simulator (SCAPS-1D). The obtained results of optimizing the thickness of the Bathocuproine (BCP) buffer layer exhibited optimum value at 5 nm, with power conversion efficiency (PCE) of 17.30 %, VOC of 1.39 V, and FF of 62.89 %. The carrier concentration was higher than 1017 cm-3 increases sharply the conversion efficiency by about 0.35-2.3 %. Further, the lower metal work function (Фm<4.3 eV) enhances the electrical parameters where the efficiency up to 21.3 %. Keywords: Solar cell, Perovskite, CH3NH3PbI3, BCP, SCAPS, Metal Work Function.
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