烃混合物:烯烃+烷烃或+环烷烃在313.15 K下的过量焓的测量和建模

2020 5th International Conference on Renewable Energies for Developing Countries (REDEC) Pub Date : 2020-06-01 DOI:10.1109/REDEC49234.2020.9163877

Mohamed Lifi, E. Montero, L. Deshayes, Natalia Muñoz-Rujas, Y. Chhiti, F. Alaoui, F. Romero

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引用次数: 3

摘要

本文报道了用准等温量热计在常压下测量含有1-己烯、环己烷和2,2,4-三甲基戊烷的二元混合物在313.15 K下的过量焓值。$H^{\ mathm {E}}$的实测数据采用NRTL和UNIQUAC模型和Redlich-Kister数学方程进行了拟合。所研究的二元混合物均表现出吸热行为。

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Measurement and modeling of excess enthalpies of hydrocarbon mixtures: Alkene + Alkane or + Cycloalkane at 313.15 K

New measurements of excess enthalpy of binary mixtures containing 1-hexene, Cyclohexane and 2,2,4-Trimethylpentane at 313.15 K are reported in this work, by using a quasi-isothermal calorimeter at atmospheric pressure. The measured data of $H^{\mathrm{E}}$ has been fitted using NRTL and UNIQUAC models, and Redlich-Kister mathematical equation. All the studied binary mixtures show an endothermic behavior.

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2020 5th International Conference on Renewable Energies for Developing Countries (REDEC)

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