用XRD和TG/DTG对天然酯老化牛皮纸进行对比研究

Yulia Erina Sari, A. Ritonga, Suwarno
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引用次数: 4

摘要

高压变压器是决定输配电系统可靠性和连续性的重要电力设备。它包括固体和液体绝缘材料。牛皮纸作为固体绝缘材料,应具有绝缘绕组连接的能力,而油变压器,除了其主要的绝缘功能外,还可用作冷却剂。采用x射线衍射(XRD)表征方法,分析了牛皮纸浸在RBD棕榈油天然酯中的加速热老化性能。采用x射线衍射(XRD)表征牛皮纸中是否存在晶体结构。牛皮纸的结晶结构是由纤维素组成的。牛皮纸的韧性是由它的无定形区域木质素决定的,木质素与纤维素结合,使其变硬。考察了热膨胀对牛皮纸结晶度的影响,探讨了热应力对牛皮纸结晶度的影响。此外,采用热重分析法对牛皮纸的热降解特性进行了研究。样品分别在120°C和150°C中陈化两周。结果还表明,在较高时效温度下加热的样品的结晶区比在较低时效温度下加热的样品下降得更快。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Comparative Study of Kraft Paper Aged in Natural Ester with XRD and TG/DTG Analysis
High voltage transformer is an essential power apparatus that determine the reliability and continuity of power transmission and distribution system. It comprises solid and liquid insulating materials. Kraft paper as solid insulation should have an ability to insulate the winding connection, while oil transformer, aside of its main function as insulation, it is also used as a coolant. This paper analyzes the accelerated thermal aging performance of kraft paper immersed in the natural ester from RBD palm oil by using X-Ray Diffraction (XRD) characterization. XRD characterization was used to determine the existence of crystalline structure in kraft paper. Crystalline structure in kraft paper is composed by cellulose. The toughness of kraft paper was determined by its amorphous region, lignin, that bind the cellulose and make them hard. The influence of thermal expansion was observed to discover the effect of thermal stress to the crystallinity of kraft paper. Besides, thermal degradation characteristics of kraft paper were examined by using thermogravimetric analysis. The sample was aged in 120°C and 150°C for two weeks. The results also show that crystalline region of the sample that heated in higher aging temperature tends to drop faster than the sample with lower aging temperature.
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