修正串联电阻模型——用积分变换确定平均浓度

A. Venezuela, R. F. Cantão, R. Ongaratto, R. Haneda
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引用次数: 0

摘要

描述膜分离过程中渗透流动的数学模型有几种。其中,串联电阻模型起着突出的作用。它考虑了膜强度、浓度极化、极化层和污垢来描述随时间的渗透流量。本文对改进的串联电阻模型进行了分析,其中将浓度极化引起的电阻定义为与跨膜压力成正比。比例常数由特定的阻力系数(由实验数据确定)与浓度边界层的厚度和平均浓度的乘积给出。由于无法通过实验得到浓度边界层内的平均浓度值,故从化学物质的守恒方程对其进行模拟。因此,本文的目的是利用广义积分变换技术求解化学种守恒方程,并应用改进的串联阻力模型来描述层流作用下葡聚糖溶液在可透管内的渗透流动。GITT对平均浓度的计算结果令人满意,并与串联阻力模型所得的渗透流量及文献报道的实验结果进行了比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
MODIFIED SERIES RESISTANCE MODEL - DETERMINATION OF MEAN CONCENTRATION BY INTEGRAL TRANSFORMATION
There are several mathematical models that describe permeate flow in membrane separation processes. Among these, the series resistance model plays a prominent role. It takes into account membrane strength, concentration polarization, polarized layer and fouling to describe the permeate flow over time. In this work, an analysis of the modified series resistance model was performed, in which the resistance by polarization of the concentration is defined as being directly proportional to the transmembrane pressure. The proportionality constant is given by the product of a specific coefficient of resistance – which is determined by means of experimental data – the thickness of the boundary layer of concentration and the mean concentration. Due to the inability to obtain experimentally the value of the average concentration within the boundary layer of concentration, its simulation is carried out from the conservation equation of the chemical species. Thus, the objective of the present work was to solve the equation of the conservation of chemical species using GITT (Generalized Integral Transform Technique) and apply the modified series resistance model to describe the permeate flow of a solution of dextran through a permeable tube under laminar flow. GITT provided satisfactory results for the mean concentration, verified by comparison with the permeate flow obtained by the series resistance model with experimental results reported in the literature.
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