一些硫醚类化合物的合成与表征

Abdulraoof saleh, Raed k. Zaidan
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引用次数: 0

摘要

本研究以廉价的天然原料或塑料垃圾为原料,如橘子皮中的柠檬烯为原料,利用勺叉塑料等塑料垃圾的热降解(裂解)制备苯乙烯为原料,采用巯基点击反应制备了一些硫醚化合物,并获得了不同的反应条件,如柠檬烯与巯基乙酸反应生成2-(4-甲基环己基-3-烯-1-基)丙基)硫基乙酸;其中反应是放热的,反应速度很快,而苯乙烯则需要水或甘油等催化剂与巯基乙酸通过亲核加成反应生成2-(苯乙基硫)乙酸。通过室温下的抗马尔可尼科夫规则,以高收率制备了所合成的硫醚化合物,并通过FT- IR和H-NMR进行了表征。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and characterization of some thioether compounds by thiol-ene click chemistry
   In this study, some thioether compounds were prepared by thiol-ene click reaction using cheap starting materials from natural source or plastic waste such as limonene from orange peel, and styrene by thermal degradation (cracking) of plastic waste like spoon and fork plastic, and different reaction conditions were achieved, some starting material did not need any catalyst or heat like limonene reacts with thioglycolic acid to give 2-(4-methylcyclohex-3-en-1-yl)propyl)thio)acetic acid , where the reaction was exothermic and very fast, while the styrene need the catalyst such as water or glycerol to start the reaction with thioglycolic acid through nucleophilic addition to give 2-(phenethylthio)acetic acid . The synthesized thioether compounds were prepared in high yield through anti-Markonickov rule at room temperature  and diagnosed by FT- IR and H-NMR .
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