用于化学和紫外线传感器的金属氧化物薄膜

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摘要

二氧化钛(TiO2)纳米传感器的高灵敏度和快速响应的CO气体和其他材料,如甲醇和甲烷。采用喷雾热解沉积(SPD)技术,将TiO2纳米颗粒(P-25)在乙醇溶液中的胶体溶液制备成纳米多孔TiO2薄膜。最初TiO2薄膜在60℃下生长,沉积后,在650℃的烤箱中过夜,然后在450℃下退火1小时,得到锐钛矿相。采用SEM和XRD对膜的表面形貌和结构性能进行了研究。对于传感器应用,在石英衬底上制作两个相距0.25 mm的金触点。开发了一种基于TiO2薄膜电阻变化的传感和测试系统。通过质量流量控制器的CO气体(空气中2%)在200℃至350℃的不同温度范围内重复5分钟的空气和CO循环。对传感器的响应和灵敏度进行了研究。同样的仪器和传感器也分别用于检测紫外线、甲烷和甲醇。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Metal Oxide Thin Films for Chemical and UV Sensors
Highly sensitive and fast responding Titanium Dioxide (TiO2) nano sensors are developed for CO gas and other materials such as methanol and methane. Nano-porous TiO2 thin films are prepared from a colloidal solution of TiO2 nano particles (P-25) in ethanol by spray pyrolysis deposition (SPD) technique. Initially the TiO2 films are grown at 60 0C and after the deposition, backed in an oven at 65 0C overnight and then annealed at 450 0C for one hour to get anatase phase. The surface morphology and structural properties of the films are studied using SEM and XRD. For sensor applications, two gold contacts separated by 0.25 mm are made on quartz substrate. A sensing and testing system has been developed based on change in the resistance of the TiO2 film. CO gas (2% in Air) through mass flow controller is used for repeated five minutes cycles of air and CO at different temperatures in the range of 200 0C to 350 0C. Response and sensitivity of the sensor has been studied. Same apparatus and sensor is also used to detect UV, methane and methanol respectively.
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