{"title":"(水+苯酚+环己烷)三元体系在T = 298.2 K时的(液+液)平衡","authors":"H. Ghanadzadeh, Milad Sangashekan, Shahin Asan","doi":"10.4018/ijcce.2013070105","DOIUrl":null,"url":null,"abstract":"Experimental solubility curves and tie-line data for the water + phenol + 2-ethyl-1-hexanol system was obtained at T = 298.2 K and atmospheric pressure. The tie-line data was determined by techniques karl-fischer and refractometry. This ternary system exhibits type-2 behavior of LLE. Distribution coefficients and separation factors were measured to evaluate the extracting ability of the solvent. The consistency of the experimental tie-line data was determined through the Othmer-Tobias and Bachman equations. The data were correlated with the NRTL a = 0.25 and UNIQUAC models and the parameters estimated present root mean square deviations below 0.50%.","PeriodicalId":132974,"journal":{"name":"Int. J. Chemoinformatics Chem. Eng.","volume":"1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2013-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"(Liquid + Liquid) Equilibrium for Ternary System of (Water + Phenol + Cyclohexane) at T = 298.2 K\",\"authors\":\"H. Ghanadzadeh, Milad Sangashekan, Shahin Asan\",\"doi\":\"10.4018/ijcce.2013070105\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Experimental solubility curves and tie-line data for the water + phenol + 2-ethyl-1-hexanol system was obtained at T = 298.2 K and atmospheric pressure. The tie-line data was determined by techniques karl-fischer and refractometry. This ternary system exhibits type-2 behavior of LLE. Distribution coefficients and separation factors were measured to evaluate the extracting ability of the solvent. The consistency of the experimental tie-line data was determined through the Othmer-Tobias and Bachman equations. The data were correlated with the NRTL a = 0.25 and UNIQUAC models and the parameters estimated present root mean square deviations below 0.50%.\",\"PeriodicalId\":132974,\"journal\":{\"name\":\"Int. J. Chemoinformatics Chem. Eng.\",\"volume\":\"1 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Int. J. Chemoinformatics Chem. Eng.\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4018/ijcce.2013070105\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Int. J. Chemoinformatics Chem. Eng.","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4018/ijcce.2013070105","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
得到了水+苯酚+ 2-乙基-1-己醇体系在T = 298.2 K和常压条件下的实验溶解度曲线和联络线数据。系线数据由卡尔费歇尔法和折射法测定。该三元体系表现出LLE的2型行为。测定了溶剂的分布系数和分离系数,评价了溶剂的提取能力。利用other - tobias方程和Bachman方程确定了实验系线数据的一致性。数据与NRTL a = 0.25和UNIQUAC模型相关,参数估计的均方根偏差小于0.50%。
(Liquid + Liquid) Equilibrium for Ternary System of (Water + Phenol + Cyclohexane) at T = 298.2 K
Experimental solubility curves and tie-line data for the water + phenol + 2-ethyl-1-hexanol system was obtained at T = 298.2 K and atmospheric pressure. The tie-line data was determined by techniques karl-fischer and refractometry. This ternary system exhibits type-2 behavior of LLE. Distribution coefficients and separation factors were measured to evaluate the extracting ability of the solvent. The consistency of the experimental tie-line data was determined through the Othmer-Tobias and Bachman equations. The data were correlated with the NRTL a = 0.25 and UNIQUAC models and the parameters estimated present root mean square deviations below 0.50%.