经优化的玻碳电极制备砷(III)纳米传感器

C. V, V. G, S. M., H. R, S. K
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引用次数: 0

摘要

污染和有毒废物在可怕的健康威胁中扮演着最重要的角色。水,生命中最重要的对象,在没有杂质的情况下被用尽。砷- III超过10微克每升(µg/L)被认为是有毒的自然寿命,其根源肺癌或皮肤黑色素瘤和心脏疾病,诱变的危险作用。地下水和海水中存在的砷杂质可能会对海洋生物的健康造成危害。砷净化需要严格批准所有的水净化方法。现有的传统方法体积大、成本高、耗时长,而且需要化学家来操作。采用金-金修饰的GCE-碳玻璃电极,在0.55摩尔硫酸中对水中砷杂质限量的标定系统进行了测试。在搅拌装置上,在0.55 mol H2SO4和HAuCl4.3H2O -硫酸和氯金酸溶液中,使用从−0.599到0.599 V的不间断转向电压,将金原子沉积在GCE上以增强。采用脉冲差分伏安法、cv -循环伏安法、LSV-线性扫描伏安法、CSV -阴极溶出伏安法和阳极溶出伏安法(ASV)对样品进行检测。优化后的传感器条在−0.94 V下转换10秒,LOD为0.2个单位/十亿(ppb),而WHO-World Health Organization规定的饮用水中砷的最大污染水平(MCL)为10 ppb(10µg/L)。最后,对制备的纳米传感丝网印刷触角条进行了DPV模式对水中铅、银、金、铋、铜等大宗金属污染物的检测。开发了一种用于检测大块金属污染物的芯片实验室- LOC用户友好型系统。它促进了更快、更便宜、便携、自动化、用户友好和精确的检测。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fabrication of Arsenic (III) Nano Sensor After Optimising by Glassy Carbon Electrode
Contamination and toxic waste are acting the most important role in horrible health threats. Water, the greatest important object for lifetime and is used up without the awareness of impurities. Arsenic - III beyond 10 micro grams per liter (µg/L) is considered as toxic to natural lifespan which roots lung cancer or skin melanoma and cardiac disease, mutagenic hazardous effects. Impurity of Arsenic takes place in ground and oceanic water may perhaps healthiness risk towards marine living things. Arsenic purification needs severely approved in all methods for water decontamination. The existing - conventional methods are bulky, costly, time consuming and need chemist to operate. An extraordinary system for the calibration for recognizing of arsenic impurity limits in water were tested by GCE- carbon glassy electrode modified by Gold-Au in 0.55 Moles of Sulphuric acid. Au- gold atoms were deposited on GCE for enhancement using Steering voltage uninterruptedly applying from −0.599 to 0.599 V in 0.55 Moles of H2SO4 & HAuCl4.3H2O - Sulphuric Acid & Chloro Auric Acid solution in the chemical setup on the stirrer. The strip was tested by Pulse Differential Voltammetry, CV-Cyclic Voltammetry, LSV- Linear Sweep Voltammetry, CSV - Cathodic Stripping Voltammetry and Anodic Stripping Voltammetry (ASV). After optimization, the fabricated sensor strip was succeeded a LOD as 0.2 measures per Billion (ppb) with 10 seconds of transformation at −0.94 V whereas the Maximum Contamination Level (MCL) of Arsenic by WHO-World Health Organization is 10 ppb (10 µg/L) in drinking water. Finally, the fabricated Nano sensing screen printed feeler strip was also examined for many bulk metal pollutants detection like Lead, Silver, Gold, Bismuth and Copper in water by DPV Mode at a time. Lab On Chip - LOC user friendly system was developed for bulk metal pollutants. It facilitated faster, cheaper, portable, automated, user friendly and precise detection.
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