混合正极材料对锂离子电池的协同效应

Chunchi Lu, Ying Wang, Ya Ren
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引用次数: 0

摘要

锂离子电池在充放电过程中,电池内部反应温度发生变化,由于三元正极材料的热稳定性不稳定,影响了电池的正常工作,也影响了电池的可用容量。许多研究者将两种正极材料混合制备电极,从而提高了电极的速率性能和极化性能。混合电极的活性物质主要由两种或两种以上的锂插层化合物物理混合而成。与单一活性材料相比,混合电极的目的是平衡两种或两种以上活性材料的性能。以三元材料为研究对象,改性方法是采用研磨法将磷酸铁锂(LiFePO4)与三元正极材料LiNi1/3co1/3Mn1/3 (NCM)以合适的质量比与极板混合搅拌,组装成锂离子电池,然后探索其各种特性。混合材料电极采用场发射扫描电镜、红外光谱和x射线衍射对其表面结构、化学成分进行表征,然后采用蓝电测试设备对混合正极材料的电化学性能进行测量,测试循环性能和速率;并利用电化学工作站对锂离子电池进行伏安曲线测试和电化学阻抗测试,研究混合正极材料的容量可逆性和电化学极化程度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synergistic effect of mixed cathode materials on lithium-ion batteries
During the charging and discharging of lithium-ion batteries, the internal reaction of the battery changes in temperature, because the thermal stability of the ternary cathode material is not stable, it affects the normal operation of the battery and also affects the available capacity of the battery. Many researchers have mixed two positive electrode materials to prepare electrodes and then improved the rate performance and polarization of the electrodes. The active material of the mixed electrode is mainly made by physical mixing of two or more lithium intercalation compounds. Compared with a single active material, the purpose of a mixed electrode is to balance the performance of two or more active materials. Taking the ternary material as the research object, the modification method is to use the grinding method to mix and stir the lithium iron phosphate (LiFePO4) and the ternary cathode material LiNi1/3co1/3Mn1/3 (NCM) with an appropriate mass ratio to the electrode plates to assemble a lithium ion battery and then explore their various characteristics. The mixed material electrodes uses field emission scanning electron microscopy, infrared spectroscopy and X-ray diffraction to characterize the surface structure, chemical composition, then uses blue electricity test equipment to measure the electrochemical performance of the mixed cathode material, test cycle performance and rate, and use electrochemical workstation to test the volt-ampere curve and electrochemical impedance test of the lithium-ion battery to study the capacity reversibility and electrochemical polarization degree of the mixed cathode material.
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