磷酸氧钛Na4TiO(PO4)2作为钠离子电池的高性能电极材料

Chaimae Hamdouchi, Abdelwahed Chari, Marwa Tayoury, J. Alami, A. El Bouari, M. Dahbi
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引用次数: 1

摘要

采用溶胶-凝胶法制备了Na4TiO(PO4)2/C复合钠离子电池负极材料。为了考察所制备材料的结构和电化学性能,研究了不同的表征方法。x射线衍射结果表明,所制备的负极能够形成无杂质的纳米颗粒,并在P2/c空间群上结晶。此外,恒流循环试验表明,在25mA/g电流下,Na4TiO(PO4)2/C可提供160 mAh/g的初始放电容量,在20次循环后具有优异的循环稳定性(99%)和高可逆性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Titanium Oxy-phosphate Na4TiO(PO4)2 as High-performance Electrode Material for Sodium-ion Batteries
The Na4TiO(PO4)2/C composite sodium-ion battery anode material has been prepared by a facile sol-gel route . In order to investigate the structural and electrochemical performances of the prepared material, different characterization methods were investigated. From the X-Ray Diffraction, the prepared negative electrode showed its ability to form impurity- free nanoparticles, which are crystallized at the space group P2/c. In addition, galvanostatic cycling tests have revealed that the Na4TiO(PO4)2/C can deliver an initial discharge capacity of 160 mAh/g at a current rate of 25mA/g, with excellent cycling stability after 20 cycles (99 %), and high reversibility.
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