M. Aqil, A. Aqil, Farid Ouahib, C. Detrembleur, C. Jérôme, Abdelrahman El Idrissi
{"title":"以PTA为有机自由基电池活性材料的新合成路线","authors":"M. Aqil, A. Aqil, Farid Ouahib, C. Detrembleur, C. Jérôme, Abdelrahman El Idrissi","doi":"10.1109/IRSEC.2016.7984033","DOIUrl":null,"url":null,"abstract":"A novel synthetic route toward a macromolecule with linear backbones that bear pendant stable radical groups is described. For this purpose we synthesis a new acrylate tempo monomer (4-acryloyloxy-1-((1-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine (APEOT)) which is thermally not stable and undergo C-O bond homolysis at higher temperatures accompanied by the generation of radicals. The polymerization of alkoxyamine-based monomer was investigated by free radical polymerization. In addition, the cycleperformance of the ORB with the cathode based on the radical polymer were studied.","PeriodicalId":180557,"journal":{"name":"2016 International Renewable and Sustainable Energy Conference (IRSEC)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2016-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"A novel synthetic route toward a PTA as active materials for organic radical batteries\",\"authors\":\"M. Aqil, A. Aqil, Farid Ouahib, C. Detrembleur, C. Jérôme, Abdelrahman El Idrissi\",\"doi\":\"10.1109/IRSEC.2016.7984033\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel synthetic route toward a macromolecule with linear backbones that bear pendant stable radical groups is described. For this purpose we synthesis a new acrylate tempo monomer (4-acryloyloxy-1-((1-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine (APEOT)) which is thermally not stable and undergo C-O bond homolysis at higher temperatures accompanied by the generation of radicals. The polymerization of alkoxyamine-based monomer was investigated by free radical polymerization. In addition, the cycleperformance of the ORB with the cathode based on the radical polymer were studied.\",\"PeriodicalId\":180557,\"journal\":{\"name\":\"2016 International Renewable and Sustainable Energy Conference (IRSEC)\",\"volume\":\"1 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2016 International Renewable and Sustainable Energy Conference (IRSEC)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/IRSEC.2016.7984033\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2016 International Renewable and Sustainable Energy Conference (IRSEC)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IRSEC.2016.7984033","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A novel synthetic route toward a PTA as active materials for organic radical batteries
A novel synthetic route toward a macromolecule with linear backbones that bear pendant stable radical groups is described. For this purpose we synthesis a new acrylate tempo monomer (4-acryloyloxy-1-((1-phenylethyl)oxy)-2,2,6,6-tetramethylpiperidine (APEOT)) which is thermally not stable and undergo C-O bond homolysis at higher temperatures accompanied by the generation of radicals. The polymerization of alkoxyamine-based monomer was investigated by free radical polymerization. In addition, the cycleperformance of the ORB with the cathode based on the radical polymer were studied.
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