斯里兰卡木棉提取纳米纤维素作为聚丙烯聚合物基体填料的有效性研究

C. D. Jayaweera, D. Karunaratne, S. Bandara, S. Walpalage
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引用次数: 5

摘要

木棉(Ceiba pentandra)是斯里兰卡一种常见的植物。它在废水处理、生物医学领域和生活中的应用非常广泛。研究了五角草纳米纤维素在聚丙烯聚合物基体中的填充性能。对酸水解提取的纳米纤维素进行进一步处理,以避免其强度下降并增加其与聚合物基质的相容性。在扫描电镜下研究了提取的纤维素的形貌,发现在纳米尺度上存在纳米纤维和厚度在100 ~ 1000nm之间的薄片。采用挤压法制备聚丙烯与纳米纤维素复合材料。测试了复合材料的力学、热、形态和理化性能。聚丙烯/纤维素复合材料的拉伸模量和抗撕裂性能均有显著提高。然而,缺乏界面相互作用会对某些力学性能产生不利影响。通过对比不同速度和停留时间制备的复合材料的力学性能测试结果,简要研究了填料分散对复合材料力学性能的影响。虽然热重分析发现初始分解温度略有提高,但热性能并未发生显著变化。观察了填料在聚合物基体中的分布,并从中观察到纳米级的分散。用x射线衍射法测定提取的纤维素的结晶度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of the effectiveness of nanocellulose extracted from Sri Lankan Kapok, as a filler in Polypropylene polymer matrix
Kapok (Ceiba pentandra) is a commonly available plant in Sri Lanka. Its application in waste water treatment, biomedical field and domestic uses is numerous. The purpose of this research is to investigate the effectiveness of nanocellulose extracted from Ceiba pentandra, as a filler in Polypropylene polymer matrix. Nanocellulose extracted from acid hydrolysis was further treated to avoid deterioration of its strengths and to increase its compatibility with the polymer matrix. The morphology of the extracted cellulose was studied under scanning electron microscopy, which revealed the existence of nanofiber and flakes of thickness in the nano dimension between 100 nm to 1000nm. Composites of Polypropylene and nanocellulose were prepared by extrusion. Mechanical, thermal, morphological and physio chemical properties of the composites were tested. The PP/cellulose composites demonstrated a remarkable improvement of tensile modulus and tear resistance. However lack of interfacial interactions detrimentally affected certain mechanical properties. The effect of dispersion of filler on mechanical properties was also briefly studied by comparing results of mechanical tests of composites prepared at different speeds and residence times in the extruder. Significant changes in the thermal properties weren't noted, although a slight improvement of the initial decomposition temperature was noted in the thermal gravimetric analysis. The distribution of the filler in the polymer matrix was observed from which nano level dispersion was observed. X-Ray diffraction was carried out to determine the crystallinity of the extracted cellulose.
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