应用方面的超细固氮粉(SFP)在空气中燃烧现象的利用

A. Gromov, A. Ilyin, E.M. Popenko, T. Khabas, V. Vereshchagin
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引用次数: 0

摘要

众所周知,用Gaber法合成氨是在高温(300-400/spl℃)和压力(35-100 MPa)的非均相铁催化剂上,以纯氮和氢为原料,在恶劣条件下进行的。现在是化学空气固氮的工业过程。创造更有效的氨合成方法,降低成本,并在较软的条件下进行,是一个紧迫的问题。前面已经证明,在SFP Al在空气中燃烧的自发过程中,存在着固氮作用。在一定条件下,最终燃烧产物为19.0%以上。被发现。连接的氮作为氮化铝独立相在水中水解形成氨。利用廉价的AlN合成氨的新方法,在工业生产中获得了SFP Al燃烧,将使产品的成本价格降低200%甚至更多。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Applied aspects of nitrogen fixation by superfine powders (SFP) combustion in air phenomenon using
It is known that the synthesis of ammonia using the Gaber method is carried out from pure nitrogen and hydrogen in severe conditions on the heterogeneous iron catalyst at high temperatures (300-400/spl deg/C) and pressure (35-100 MPa). Now it is an industrial process of chemical air nitrogen fixation. Creation of more effective ways of ammonia synthesis allowing lowering of expenses and carrying out the process in softer conditions, is an urgent problem. It was shown earlier, that in spontaneous process at SFP Al burning in air, there is a nitrogen fixation. Under certain conditions, final combustion products of more than 19.0% wei. are found. The connected nitrogen as aluminum nitride independent phase at hydrolysis in water form the ammonia. The new way of synthesising of ammonia using cheap AlN, received at SFP Al burning in industrial manufacture will allow lowering of the cost price of a product of 200% and more.
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