聚苯胺/氧化石墨烯纳米复合材料超级电容器的循环伏安法和恒流充放电分析

M. Abid, M. Radzi, M. Mupit, H. Osman, R. F. Munawar, K. F. Samat, M. Suan, Kazuki Isomura, M. R. Islam
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引用次数: 5

摘要

超级电容器具有可逆性好、寿命长、功率密度高等优点,是一种应用于众多领域的能源器件。然而,与电池相比,它的能量存储容量减少,交叉串联高,限制了它的普遍使用。尽管超级电容器的输出功率相对较高,并且得到了广泛的应用,但总的来说,它们的效率仍然存在很大的疑问和模糊性,特别是当它与锂离子电池相比时。这种不一致是由于测试方法缺乏标准化,以及在确定其电阻后超级电容器的强度容量的确定性。为此,本文制备了氧化石墨烯(GO)和聚苯胺(PANI)纳米复合超级电容器电极,并通过循环伏安法和恒流充放电分析对其性能进行了研究。采用改进Hummers法合成氧化石墨烯,采用氧化聚合化学合成聚苯胺。采用聚苯胺/氧化石墨烯纳米复合材料制备了三种不同的电极组合,分别标记为PGO30、PGO50和PGO70。本文将对该电极的电化学性能进行总结。结果表明,与其他复合电极相比,PGO50电极(50%聚苯胺/50%氧化石墨烯)的计算电容最佳,为19.71 F/g。这可能是由于聚苯胺和氧化石墨烯具有良好的导电分布。研究结果对纳米复合材料制备超级电容器电极具有重要的指导意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Cyclic Voltammetry and Galvanostatic Charge-Discharge Analyses of Polyaniline/Graphene Oxide Nanocomposite based Supercapacitor
Supercapacitor is an energy device that is applicable in numerous fields because of its excellent reversibility, long life and high power density. Nevertheless, its universal use is restricted by the reduced energy storage capacity and its high crossed series compared to batteries. Even with the relatively high-level output and extensive use of supercapacitor, there is still substantial doubt and ambiguity as to their efficiency in general, especially when it is compared to lithium-ion batteries. The inconsistencies are attributable both to the lack of standardization of the test methods and to the certainty of the strength capacity of the supercapacitor after their resistance has been identified. Therefore, in this work, graphene oxide (GO) and polyaniline (PANI) nanocomposite supercapacitor electrode was fabricated and the performance was investigated by means of cyclic voltammetry and galvanostatic charge-discharge analyses. GO was synthesized using improve Hummers method and PANI using oxidative polymerization chemical synthesis. Three different electrode’s compositions were prepared using PANI/GO nanocomposite and labelled as PGO30, PGO50 and PGO70. This article will conclude the electrochemical performance of the electrode. From the results, it was found that PGO50 electrode (50% PANI/50% GO) has the best calculated capacitance with 19.71 F/g compared to the other composite electrodes. This may be attributed from the good electrical conductivity distribution of PANI and graphene oxide. The findings of the work may significantly drive the future of supercapacitor electrode from nanocomposite related materials.
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