{"title":"表面发生可逆电化学反应时平面伏安电极的时域计量特性","authors":"Krzysztof Suchocki","doi":"10.1117/12.2248337","DOIUrl":null,"url":null,"abstract":"The study deals with metrological characteristics of the flat voltammetric electrode used for determination of ions concentration by the DC voltammetric method, where a reversible reaction of electrochemical oxidation/reduction takes place on the surface. The analysis shows that such voltammetric electrode acts as a transducer of the first order, where the input signal is a concentration of marked ions in tested solution and the output signal is the current associated with a reversible reaction of oxidation / reduction. Metrological characteristics of such electrode in the time domain are determined by its sensitivity and time constant. The values of these parameters are defined by measurements of characteristics of the voltammetric electrode, polarization voltage and marked ions. To determine the effect of a particular volume of each of these parameters several numerical simulations are presented.","PeriodicalId":101814,"journal":{"name":"Scientific Conference on Optical and Electronic Sensors","volume":"10 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2016-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface\",\"authors\":\"Krzysztof Suchocki\",\"doi\":\"10.1117/12.2248337\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The study deals with metrological characteristics of the flat voltammetric electrode used for determination of ions concentration by the DC voltammetric method, where a reversible reaction of electrochemical oxidation/reduction takes place on the surface. The analysis shows that such voltammetric electrode acts as a transducer of the first order, where the input signal is a concentration of marked ions in tested solution and the output signal is the current associated with a reversible reaction of oxidation / reduction. Metrological characteristics of such electrode in the time domain are determined by its sensitivity and time constant. The values of these parameters are defined by measurements of characteristics of the voltammetric electrode, polarization voltage and marked ions. To determine the effect of a particular volume of each of these parameters several numerical simulations are presented.\",\"PeriodicalId\":101814,\"journal\":{\"name\":\"Scientific Conference on Optical and Electronic Sensors\",\"volume\":\"10 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-11-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scientific Conference on Optical and Electronic Sensors\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1117/12.2248337\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scientific Conference on Optical and Electronic Sensors","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1117/12.2248337","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Metrological characteristics of the flat voltammetric electrode in time domain with a reversible electrochemical reaction running on the surface
The study deals with metrological characteristics of the flat voltammetric electrode used for determination of ions concentration by the DC voltammetric method, where a reversible reaction of electrochemical oxidation/reduction takes place on the surface. The analysis shows that such voltammetric electrode acts as a transducer of the first order, where the input signal is a concentration of marked ions in tested solution and the output signal is the current associated with a reversible reaction of oxidation / reduction. Metrological characteristics of such electrode in the time domain are determined by its sensitivity and time constant. The values of these parameters are defined by measurements of characteristics of the voltammetric electrode, polarization voltage and marked ions. To determine the effect of a particular volume of each of these parameters several numerical simulations are presented.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
