{"title":"极性分子中的转动里德伯态","authors":"V. Chernov, D. L. Dorofeev, B. Zon","doi":"10.1364/shbs.1994.wd59","DOIUrl":null,"url":null,"abstract":"The molecular Rydberg states have more complicated structure than the atomic ones. The phenomenon is due to the rotational spectrum being characteristic of molecules unlike atoms. Inasmuch as the distance between rotational levels of the molecular core is comparable to the distance between high excited levels in the pure Coulomb field, rotational states mix with Rydberg ones and form rotational-Rydberg (ro-Ry) states.","PeriodicalId":443330,"journal":{"name":"Spectral Hole-Burning and Related Spectroscopies: Science and Applications","volume":"04 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rotational Rydberg states in polar molecules\",\"authors\":\"V. Chernov, D. L. Dorofeev, B. Zon\",\"doi\":\"10.1364/shbs.1994.wd59\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The molecular Rydberg states have more complicated structure than the atomic ones. The phenomenon is due to the rotational spectrum being characteristic of molecules unlike atoms. Inasmuch as the distance between rotational levels of the molecular core is comparable to the distance between high excited levels in the pure Coulomb field, rotational states mix with Rydberg ones and form rotational-Rydberg (ro-Ry) states.\",\"PeriodicalId\":443330,\"journal\":{\"name\":\"Spectral Hole-Burning and Related Spectroscopies: Science and Applications\",\"volume\":\"04 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectral Hole-Burning and Related Spectroscopies: Science and Applications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1364/shbs.1994.wd59\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectral Hole-Burning and Related Spectroscopies: Science and Applications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1364/shbs.1994.wd59","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The molecular Rydberg states have more complicated structure than the atomic ones. The phenomenon is due to the rotational spectrum being characteristic of molecules unlike atoms. Inasmuch as the distance between rotational levels of the molecular core is comparable to the distance between high excited levels in the pure Coulomb field, rotational states mix with Rydberg ones and form rotational-Rydberg (ro-Ry) states.
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