极性分子中的转动里德伯态

Spectral Hole-Burning and Related Spectroscopies: Science and Applications Pub Date : 1900-01-01 DOI:10.1364/shbs.1994.wd59

V. Chernov, D. L. Dorofeev, B. Zon

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摘要

分子里德伯态比原子里德伯态具有更复杂的结构。这种现象是由于分子的旋转光谱不同于原子。由于分子核旋转能级之间的距离与纯库仑场中高激发能级之间的距离相当，转动态与里德伯态混合形成旋转-里德伯态(ro-Ry)。

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Rotational Rydberg states in polar molecules

The molecular Rydberg states have more complicated structure than the atomic ones. The phenomenon is due to the rotational spectrum being characteristic of molecules unlike atoms. Inasmuch as the distance between rotational levels of the molecular core is comparable to the distance between high excited levels in the pure Coulomb field, rotational states mix with Rydberg ones and form rotational-Rydberg (ro-Ry) states.

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Spectral Hole-Burning and Related Spectroscopies: Science and Applications

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