已知离子强度的缓冲溶液

Cerdà Víctor, Phansi Piyawan
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引用次数: 0

摘要

pH缓冲溶液是当加入或稀释适量的强酸或强碱时pH值变化最小的溶液。最常见的缓冲液是在中间pH区使用的缓冲液,由酸碱共轭对(HA/A-)组成,分别以Ca和Cb作为酸和碱的分析浓度。溶液的缓冲能力是在加入酸或碱时,对其保持pH值的有效性的度量。在Windows 10环境下工作的三个新程序已经开发出来。第一个,BUFFER程序,允许制备已知离子强度的缓冲液,而不需要添加惰性电解质,计算pH值和缓冲容量。另一方面,BRÖMSTED方法允许应用牛顿-拉夫森方法计算共轭酸碱体系的pH值。在这项工作中,描述了另外两个程序,一个应用Brömsted方法对单质子酸和另一个新的二质子酸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Buffer Solutions of known Ionic Strength
pH buffer solutions are those in which minimal pH variations occur when moderate amounts of strong acids or bases are added or diluted. The most common buffers are those used in the intermediate pH zone and are made up of an acid-base conjugate pair (HA/A-), with Ca and Cb as analytical concentrations of acid and base respectively. The buffer capacity of a solution is the measure of its effectiveness in preserving the pH value when adding an acid or a base. Three new programs working under the Windows 10 environment have been developed. The first one, the BUFFER program, allows to prepare buffers of known ionic strength without the need of adding an inert electrolyte, calculating the pH and buffering capacity. On the other hand, the BRÖMSTED method allows calculating the pH of conjugated acid-base systems applying the Newton-Raphson method. In this work two more programs are described, one applying the Brömsted method to monoprotic acids and another new one to diprotic acids.
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