改进了地下排水系统钢筋混凝土结构碳化评价的计算方法和试验方法

M. Sukach, V. Chigarov, I. Chebotar
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摘要

混凝土碳化导致混凝土碱度降低,孔隙中氢离子数量增加,是导致钢筋锈蚀、裂缝形成和随后结构承载能力降低的主要因素之一。混凝土碳化深度的研究就是测定不同深度下孔隙液的pH值。有一些装置可以自动维持给定的二氧化碳浓度,根据混凝土与二氧化碳的中和(碳化)率的数据来确定混凝土对二氧化碳的扩散渗透性。基本上,该方法旨在用于技术开发和混凝土成分设计,在非腐蚀性和腐蚀性气体环境中提供结构的长期维护,因为芯片在测试前不立即准备,在达到设计龄期后与试剂一起放置在装置中7天。但要直接测定施工现场或物体的炭化程度,往往采用pH法,即指示剂法测定pH值。为了评估氢离子的浓度,使用酸碱指示剂-有机物-染料,其颜色取决于所得结果的pH值,定义碳化深度的算法包括以下几个动作。考虑老化和腐蚀损伤程度的混凝土碳化深度定义的改进公式在最终公式中输入相应的系数kst和kkor: hcarb = {(2D C τ) / (mo kst kkor)} 1/2,其中CO2在现有钢筋混凝土结构混凝土中的有效扩散系数由条件D = (mo δ2) / (2C t)确定。中和层的厚度δ是用物理化学方法(酚酞溶液或深度计)在现有结构上实验测定的。空气中的CO2浓度C应通过直接从结构中提取的空气样品的化学分析来测定,或取≈0.03%。Re.混凝土的承载力mo由公式mo = 0.4 (C p f)确定,取水泥掺量,kg / 1m3分别为混凝土的强度。混凝土中和度等于f = 0.5。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improvement of the calculation and experimental method of evaluation of carbonization of reinforced concrete structures of sewerage underground systems
Carbonization of concrete leads to a decrease in the alkalinity of concrete, an increase in the number of hydrogen ions in the pores, is one of the main factors that lead to corrosion of reinforcement, the formation of cracks and the subsequent reduction of load-bearing capacity of structures. The study of the depth of carbonization of concrete is to determine the pH of the pore liquid at different depths. There are devices with automatic maintenance of a given concentration of carbon dioxide, to determine the diffusion permeability of concrete to carbon dioxide, based on data on the rate of neutralization (carbonization) of concrete with carbon dioxide. Basically, this method is intended for use in the development of technology and design of concrete composition, providing long-term maintenance of structures in non-aggressive and aggressive gaseous environments, as chips are not prepared immediately before the test and after reaching the design age are placed in the installation with reagents for 7 days. But to determine the carbonization directly on the construction site or object often use the pH method, i.e. the indicator method of pH determination. To assess the concentration of hydrogen ions used acid-base indicators - organic substances – dyes, the color of which depends on the pH from the obtained results the algorithm of definition of depth of carbonization consists in the following actions. The improved formula of definition of depth of carbonization of concrete taking into account degree of aging and corrosion damages for what in the final formula the corresponding coefficients kst and kkor are entered: hcarb = {(2D˖C˖τ) / (mo˖kst ˖kkor)} 1/2, where the effective diffusion coefficient of CO2 in the concrete of the existing reinforced concrete structure, which is determined by the condition D = (mo˖δ2) / (2C˖t ). The thickness of the neutralized layer δ is determined experimentally on an existing structure using a physicochemical method (phenolphthalein solution or using depth gauges. .Concentration of CO2 in air C should be determined by chemical analysis of air samples taken directly from the structure or take ≈ 0.03%. Re. the ability of concrete mo is determined by the formula mo = 0.4 (C˖p˖f), taking the amount of cement, kg per 1m3, respectively, the strength of concrete. neutralization of concrete is equal to f = 0.5.
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