低温法制备Zn1-xMgxO纳米粒子的光学性质

M. Ghosh, A. Raychaudhuri
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引用次数: 3

摘要

本文报道了低温溶液法合成镁取代氧化锌(Zn1-xMgxO)纳米颗粒(~8 ~ 10nm)。我们可以达到x=0.075而不分离MgO。XRD数据的Rietveld分析证实了纤锌矿结构,并且随着x的增加,晶格连续压实。带隙也随着x的增加而增强,并在x=0.075时达到4eV的值。吸收也显示了对Mg取代的激发吸收的持久性。纳米颗粒在室温下表现出近带边光发光(PL),在Mg掺入时表现出蓝移。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optical properties of Zn1-xMgxO nano-particles obtained by low temperature method
In this paper we report synthesis of Magnesium substituted Zinc Oxide (Zn1-xMgxO) nano-particles (~8-10nm) by low temperature solution route. We could reach upto x=0.075 without MgO getting segregated. Rietveld analysis of the XRD data confirms the Wurzite structure and a continuous compaction of the lattice as x increases. The bandgap also gets enhanced as x is increased and reaches a value of 4eV for x=0.075. The absorption also shows persistence of the excitoinc absorption on Mg substitution. The nanoparticles show near band edge photo luminescence (PL) at room temperature which shows blue shift on Mg incorporation.
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