人工神经网络与γ-Fe2O3纳米粒子包覆QCM传感器在SO2气敏特性估计中的应用

Vinh Nguyen Thanh, Tran Quoc Tuan, Nguyen Van Cuong, Cao Xuan Truong, Nguyen Van Quy
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引用次数: 1

摘要

采用共沉淀法合成了γ-Fe2O3纳米颗粒(NPs),并在200℃环境空气中进行了6小时的退火处理。在石英晶体微天平(QCM)的活性电极上涂覆γ-Fe2O3纳米粒子,制备了质量型传感器。实验结果表明,基于γ-Fe2O3 NPs的QCM传感器在室温下对2.5 ~ 20ppm范围内的SO2气体具有较高的响应和重复性。此外,γ-Fe2O3 NPs包覆QCM传感器的频移(DF)和单位面积二氧化硫吸附质量(Dm)的变化与γ-Fe2O3 NPs的质量密度和二氧化硫浓度有关。采用Levenberg-Marquardt优化的人工神经网络(ANN)模型对γ-Fe2O3 NPs包覆QCM传感器的DF和Dm进行了处理。模型验证的结果证明,该方法在实验值和预测值之间是可靠的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Application of an artificial neural network and QCM sensor coated with γ-Fe2O3 nanoparticles for estimation of SO2 gas sensing characteristics
γ-Fe2O3 nanoparticles (NPs) were synthesized by co-precipitation method and a following annealing treatment at 200 °C in ambient air for 6 hours. A mass-type sensor was prepared by coating γ-Fe2O3 NPs on the active electrode of quartz crystal microbalance (QCM). The obtained results of the γ-Fe2O3 NPs based QCM sensor indicate the high response and good repeatability toward SO2 gas in the range of 2.5 – 20 ppm at room temperature. Moreover, the frequency shift (DF) and change in mass of SO2 adsorption per unit area (Dm) of the γ-Fe2O3 NPs coated QCM sensor have a relationship with the mass density of γ-Fe2O3 NPs and SO2 concentrations. The artificial neural network (ANN) model using Levenberg-Marquardt optimization was used to handle the DF and Dm of the γ-Fe2O3 NPs coated QCM sensor. The results of the model validation proved to be a reliable way between the experiment and prediction values.
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