Nd (Mg½Ti½)O3 (NMT)钙钛矿在移动通信中的应用

Kouros Khamoushi, V. Mitić, J. Manojlovic, V. Paunovic, G. Lazovic
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引用次数: 0

摘要

利用拉曼光谱、x射线、扫描电镜、透射电镜和差示扫描量热仪(DSC)等方法,从复合化合物的角度对NMT物质的电导率、相群、空间群性质和样品的晶界进行了近似分析,样品在实验室制备和分析的频率范围为9.76 GHz。采用固态常规方法。所有样品在1250℃至1550℃范围内进行XRD测试,每个样品升温50℃,冷却至室温。即使在升高的温度下,结构也不会发生收缩。与La+材料相比,Nd+离子极化率提高了0.50 nm, La+材料极化率提高了0.60 nm,这导致了钙钛矿立方度的变化。这是由于Nd+ 0.127 nm阳离子的尺寸比La+小,虽然偶极子减少,但偶极子数增加,相对介电常数(εr)增大。所制得的单相材料在10 GHz饱和时质量因子Q×f = 60000,温度系数(τf) = -77 MK-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Application of Nd (Mg½Ti ½) O3 (NMT) Perovskite in Mobile Communications
The electrical conductivity, phase, and space group of property of the NMT substance and grain boundary of samples were approximated from complex compound by Raman spectroscopy, X-ray, SEM, TEM, and differential scanning calorimeter (DSC), samples prepared and analyzed in the laboratory in the frequency ranges from 9.76 GHz. The solid-state conventional method utilized. All the samples were tested by using XRD from 1250°C to 1550°C by increasing 50 degrees for every sample and cooling to the room temperature. The contraction of structure did not happen even at elevated temperature. The increase in Nd+ ion polarizability is 0.50 nm compared to La+ rare elements material, which is 0.60, this contributes to change of perovskite cubic. This is result of the smaller size of Nd+ 0.127 nm cation compared to La+ which increase number of dipoles despite the reduction of diploes and expands relative permittivity (εr). The single-phase material produced which shows quality factor Q×f = 60000 saturated at 10 GHz and temperature coefficient of (τf) = -77 MK-1.
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