非线性材料的极限特性研究

M. Savelyev, A. Gerasimenko, S. Tereshchenko, V. Podgaetsky
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引用次数: 0

摘要

考虑了激光辐射限制器(LRL)材料非线性光学特性的定义。研究了晶体结构高度完善的半导体型和金属型单壁碳纳米管(SWCNT)纳米复合材料和分散光学材料。半导体SWCNTs的数量是金属的数倍,大多数SWCNTs以独立的松散纤维的形式呈簇状呈现。这表明它的分散程度很高。在四氢呋喃中分散羧基化SWCNTs的激光在线性传输时衰减系数AC ~ 13 T0≈75%。在swcnts功能化的酞菁锌衍生物的分散中,T0 = 55-75%时AC = 13-14。在T0≈70%的温度下,基于功能化SWCNTs AC ~ 8的聚甲基丙烯酸甲酯纳米复合材料。提出了一种利用Z_scan数据同时计算光束腰半径和非线性吸收系数的新方法。得到了ZnSe、卟啉-石墨烯(石墨烯- tpp)、富勒烯-石墨烯(石墨烯-60)、含多层碳纳米管的聚氧化物(PEO/MWNT),以及聚甲基染料PD-792和PD-7098和二氰亚甲基吡喃染料DCM-627和DCM-684的非线性光学特性值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of limiting properties of nonlinear materials
Definition of nonlinear optical characteristics of substances of laser radiation limiters (LRL) was considered. Nanocomposite and disperse optical materials based on single-walled carbon nanotubes (SWCNT) of semiconducting and metal types with a high perfection of the crystal structure were investigated. The amount of semiconducting SWCNTs outnumbered metal several times Most SWCNTs were presented in clusters as separate loose fibers. It indicated a high degree of its dispersion. In the dispersion of carboxylated SWCNTs in tetrahydrofuran laser attenuation coefficient AC ~ 13 at a linear transmission T0 ≈ 75 %. In the dispersion of SWCNT functionalized zinc phthalocyanine derivatives, AC = 13-14 at T0 = 55-75%. Nanocomposites based on polymethylmethacrylate with functionalized SWCNTs AC ~ 8 at T0 ≈ 70%. A new method of simultaneous calculation of the beam waist radius and nonlinear absorption coefficient from the Z_scan data is proposed. The value of nonlinear optical characteristics of ZnSe, porphyrin-graphene (Graphene-TPP), fullerene-graphene (Graphene-60), polyethylene oxide containing multilayer carbon nanotubes (PEO/MWNT), along with polymethine dyes PD-792 and PD-7098 and dicyanomethylene pyran dyes DCM-627 and DCM-684, are obtained.
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