不同化合物中铜原子x射线吸收k边有效电荷与逆相关参数关系的推导

Rakesh Ranjan
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引用次数: 0

摘要

本文综述了XANES技术对多组分催化剂分析的贡献。对该技术的理论基础、XANES特征的能量位置和强度的解释以及用于解释催化体系XANES数据的数值方法进行了描述和讨论。系统中铜k边的XANES。研究了CuO、Cu(NO3)2、La2CuO4、CuCl2和cur,并对观察到的结构进行了跃迁。这些测量已用于计算上述体系中的第一配位键距离。观察到,这样测定的值与晶体学值相当吻合
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Derivation of Relation between a parameter of Inverse correlation and effective Charge of X-ray absorbing K-Edge of Copper atom in it’s different Compounds
The article gives an overview of the XANES technique contribution to the analysis of multi-component catalysts. The theoretical basis of the technique, the interpretation of the energy position and intensity of XANES features, and the numerical methods developed to interpret XANES data on catalytic systems are described and discussed. XANES in the K-edge of copper in the systems. CuO, Cu(NO3)2, La2CuO4, CuCl2, and CuBr have been investigated and transitions have been assigned to the observed structures. The measurements have been used for calculating the first coordination bond distance in the above systems. It is observed that the values so determined agree fairly well with crystallographic values
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