含钛磷灰石上磷灰石的形成

Tomohiro Uchino, Kana Ichikawa, Rina Mashima, K. Tamura
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引用次数: 0

摘要

湿法合成的含钛磷灰石(TMA)陶瓷在力学性能和切削性能上均优于羟基磷灰石(HAp)陶瓷。在这项研究中,我们研究了TMA在体内环境中的化学反应。每个TMA或商用羟基磷灰石粉末(HAp)通过单轴挤压形成圆形颗粒。试样在马弗炉中采用常规烧结工艺加热。部分TMA试样经碱处理和热处理处理。处理后,在37.0°C下pH为7.25的模拟体液(SBF: Kokubo’s solution)中浸泡7 d。在SBF中浸泡前后,采用XRD、SEM和ICP对样品表面进行了表征。在SBF中浸泡7d后,经碱和热处理的HAp陶瓷和TMA陶瓷表面有颗粒析出。羟基磷灰石晶体结构中的含钛影响了体内环境中磷灰石的形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Apatite Formation on Titanium Containing Apatite
Some titanium containing apatite (TMA) ceramics prepared by wet synthesis was superior to Hydroxyapatite (HAp) ceramics of mechanical property and cutting performance. In this study, we investigated chemical reaction of TMA in a body environment. Each TMA or commercial Hydroxyapatite powder (HAp) was formed to circular pellets by uniaxial pressing. The specimens were heated in muffle furnace by conventional sintering process. Some TMA specimens were dispensed by alkali and heat treatment. After the treatments, the specimens were soaked in simulated body fluid (SBF: Kokubo’s solution) at pH 7.25 at 37.0°C up to 7 days. Before and after soaking in SBF, the surfaces of the samples were characterized by XRD, SEM, and ICP. After soaking in SBF for 7days, some particles were precipitated on the surface of HAp ceramics and TMA ceramics with alkali and heat treatment. Ti-containing in the crystal structure of HAp affected apatite formation in the body environment.
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