紫外激光诱导荧光检测大气NO系统的表征

J. Bradshaw, M. Rodgers, S. Fischer, D. Davis
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引用次数: 0

摘要

在航空条件下,紫外激光荧光探测大气痕量气体已被证明能够探测到万亿分之一(ppt)范围内的大气OH该系统使用Nd:YAG泵浦染料激光器产生<。5 mJ在2819Å(通过SHG)以泵送OH的A2Σ+激发态的v ' =−1流形。使用高通量光学收集方案在3095Å上监测所得荧光。Davis等人最近报道了基于他们已经证实的OH检测系统检测大气微量气体NO、SO2和CH2O ppt水平的必要要求这里介绍的是该系统的实验细节,该系统在大气条件下已检测到ppt水平的NO。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization of a UV Laser Induced Fluorescence System for Detecting Atmospheric NO
UV laser fluorescence detection of trace atmospheric gases under airborne conditions has been proven to be capable of detecting atmospheric OH in the sub-part-per-trillion (ppt) range.1 This system used a Nd:YAG pumped dye laser to produce <.5 mJ at 2819Å (via SHG) in order to pump the v′=−1 manifold of the A2Σ+ excited state of OH. The resulting fluorescence was monitored at 3095Å using a high throughput optical collection scheme. Davis, et al. recently reported the requirements necessary for detecting ppt levels of the atmospheric trace gases NO, SO2 and CH2O based on their already proven OH detection system.2 Presented here are the experimental details of such a system which has detected NO at the ppt level under atmospheric conditions.
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