矿山废弃物:贵金属尾矿的固结特性

Brandi S. Goddard, M. Figueroa, Ahlam Abdulnabi, N. Beier
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摘要

所有的矿山加工厂都会产生废物。这些副产品包括废石和被称为“尾矿”的细粒泥浆(Beier, 2015)。尾矿处理的主要目的是去除尾矿中的水分,提高尾矿的强度和刚度(Sobkowicz and Morgenstern, 2009)。研究尾砂的岩土力学特性对了解尾砂的固结行为和促进土地复垦具有重要意义。此外,还应研究尾矿的地球化学特征,以确定酸性岩石排水(ARD)的潜在发生。当pH值低于4时,酸性岩石会发生排水,这可能导致金属在溶液中大量浸出。本文研究了大气条件下贵金属尾矿的岩土力学和地球化学行为。感兴趣的地球化学参数是pH、氧化还原电位(Eh)和电导率(Ec)。采用大应变固结试验(LSC)对试样的压缩特性进行了表征。据此,测量了尾矿在不同有效应力作用下的变形量。此外,在每个固结步骤结束时,测量了水力导率或水流速度。此外,使用标准化探针对化学参数进行了评估。尾矿在自重固结过程中表现出较高的压缩性,这是由高初始孔隙比和高初始饱和导水率共同作用的结果。此外,由于加载降低了孔隙体积,导水率随试样加载呈非线性降低。加载过程中,渗透率下降了2个数量级,从2.14E-05 m/s降至1.60E-7 m/s。从地球化学角度看,尾矿固结过程中pH值无明显变化。在这种情况下,碳酸钙的存在具有中和酸的能力。此外,由于暴露于大气中,氧化还原电位和电导率都略有增加。氧化还原电位以10 mV / d的斜率增加。电导率斜率为9 mS/cm / d。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mine Waste: Consolidation Behaviour of Precious Metal Tailings
All mine processing plants generate waste. These byproducts include waste rock and a fine-grained slurry referred to as ‘tailings’ (Beier, 2015). The primary objective of treating tailings is to remove water, to enhance strength and stiffness (Sobkowicz and Morgenstern, 2009). Studying the geotechnical properties of tailings is essential to understand consolidation behaviour and facilitate land reclamation. Moreover, the geochemical characteristics of tailings should be examined to examine the potential onset of acid rock drainage (ARD). Acid rock drainage occurs when pH falls below 4, which can cause metal heavy leaching as they become present in solution. This study investigates both the geotechnical and geochemical behaviour of precious metal tailings in atmospheric conditions. The geochemical parameters of interest are pH, redox potential (Eh) and electric conductivity (Ec). The Large Strain Consolidation test (LSC) was implemented to characterize the compressibility behaviour of the sample. Accordingly, the amount of deformation that the tailings underwent was measured as they were loaded to different effective stresses. In addition, the hydraulic conductivity or the velocity of water flow was measured at the end of each consolidation step. Furthermore, the chemical parameters were evaluated using standardized probes. The tailings exhibit high compressibility during self-weight consolidation due to a combination of high initial void ratio and a high initial saturated hydraulic conductivity. In addition, hydraulic conductivity decreases nonlinearly as the samples are loaded because loading reduces the pore volume. The permeability decreased two orders of magnitude during loading, from 2.14E-05 m/s to 1.60E-7 m/s. From the geochemical point of view, there is no significant change in pH as the tailings consolidate. In this scenario, the presence of calcium carbonate has an acid-neutralizing capacity. Moreover, there is a slight increase in both redox potential and electric conductivity due to exposure to the atmosphere. The increasing trend of redox potential had a slope of 10 mV per day. While the slope of electric conductivity was 9 mS/cm per day.
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