毛豆叶提取物在1M HCl溶液中对低碳钢的缓蚀作用

J. N. Akaaza, M. Baka, G. B. Nyior, D. Gundu, A. Ashwe
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引用次数: 0

摘要

采用失重法和动电位极化法,在室温(30)和高温(40、50、60和70)条件下,研究了板鸡叶提取物对1M HCl中低碳钢的缓蚀作用。减重技术的结果表明,抑菌效果随浸提液浓度和浸提时间的增加而增加,但随浸提液温度的升高而降低。当叶提取物浓度为0.5 g/L时,抑菌率达到81.71%。腐蚀速率随萃取物浓度的增加而降低,随温度的升高而升高。动电位极化法结果表明,在1M HCl溶液中对正负反应均有修饰作用,是一种混合型缓蚀剂。在低碳钢板上观察到提取物的吸附遵循Langmuir和Temkin吸附等温线。吸附自由能的负值为-21.35 ~ -23.03 kJ/mol。,这表明抑制剂分子被物理地自发地吸附在金属表面。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Inhibition of Mild Steel Corrosion by Leaves Extracts of Commelina benghalensis L In 1M HCl Solution
The inhibition of mild steel corrosion in 1M HCl by leaves  extracts of Commelina benghalensis L was investigated using weight loss and potentiodynamic polarization techniques at room (30  and elevated temperatures of 40, 50, 60 and 70. The results of weight loss technique showed that the inhibition efficiency increased with increase in extract concentration and exposure time but decreased with rise in temperature. The maximum inhibition efficiency obtained was 81.71 % at 0.5 g/L concentration of leaves extracts. Corrosion rates decreased with increased concentration of extracts but increased with increase in temperature. Potentiodynamic polarization method results indicated that Commelina benghalensis L is a mixed - type inhibitor as it modified both the anodic and cathodic reactions in 1M HCl solution. The adsorption of the extracts on the mild steel coupons was observed to follow Langmuir and Temkin adsorption isotherms. The negative values of Gibb’s free energy of adsorption ranged from -21.35 to -23.03 kJ/mol., this suggests that inhibitor molecules were physically and spontaneously adsorbed onto the metal surface.
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